sodium tricarbonyl(triphenylphosphino)cobaltate

Base Information

Chemical Name:sodium tricarbonyl(triphenylphosphino)cobaltate
CAS No.:33570-17-1
Molecular Formula:C₂₁H₁₅CoO₃P*Na
Molecular Weight:428.305
Hs Code.:

Synonyms:sodium tricarbonyl(triphenylphosphino)cobaltate

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Chemical Property of sodium tricarbonyl(triphenylphosphino)cobaltate

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Technology Process of sodium tricarbonyl(triphenylphosphino)cobaltate

There total 3 articles about sodium tricarbonyl(triphenylphosphino)cobaltate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10170-27-1,190336-13-1
Co₂(CO)6(PPh₃)2

: 33570-17-1
sodium tricarbonyl(triphenylphosphino)cobaltate

Guidance literature:: With sodium amalgam; In tetrahydrofuran; reduction with freshly made Na#Hg; stirred 1h under Ar in the dark; excess sodium amalgam removed; filtered (Celite, under Ar);

Reference yield:

: 10170-27-1,190336-13-1
hexacarbonyldi(triphenylphosphine)dicobalt(O)

: 33570-17-1
sodium tricarbonyl(triphenylphosphino)cobaltate

Guidance literature:: With sodium amalgam; In tetrahydrofuran; suspn. of the Co-complex was stirred with 1.5% Na/Hg under Ar atmosphere until a light yellow soln. was observed, left to stand for 1 h; clear soln. was decanted and used without isolation;
DOI:10.1021/om00147a028

Reference yield:

: 133160-49-3,116558-66-8,14564-33-1
[Co(PPh₃)2(CO)2Cl]

: 33570-17-1
sodium tricarbonyl(triphenylphosphino)cobaltate

: Na⁽¹⁺⁾*{Co(CO)2(P(C₆H₅)3)2}^(1-)*2C₄H₈O=Na{Co(CO)2(P(C₆H₅)3)2}*2C₄H₈O

Guidance literature:: With Na#Hg; tetrahydrofuran; In tetrahydrofuran; shaking with Na-amalgame;; evaporation, dissolution of residue, precipitation at -15 °C, recrystallization from THF/ether;;