1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose

Base Information

• Chemical Name: 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose
• CAS No.: 321156-96-1
• Molecular Formula: C₂₂H₁₈N₂O₁₁S
• Molecular Weight: 518.458

Synonyms:1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose

Chemical Property of 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose

There total 1 articles about 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

acetic anhydride (108-24-7) + methyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-3-thio-α-D-glucopyranoside (321156-95-0) → 1,5-di-O-acetyl-2,6-anhydro-3-O-(4-nitrobenzoyl)-2-thio-α-D-altrofuranose (321157-02-2) + methyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-3-thio-α-D-glucopyranoside + 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose (321156-96-1) + 3,6-anhydro-1,1,5-tri-O-acetyl-2,4-di-O-(4-nitrobenzoyl)-3-thio-D-glucose

Guidance literature:

methyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-3-thio-α-D-glucopyranoside; With trifluoroacetic acid; In water; at 25 ℃; for 8h;

acetic anhydride; In pyridine; at 20 ℃; for 3h;

DOI:10.1016/S0008-6215(00)00218-4

Reference yield: 57.1%

para-nitrobenzenethiol (1849-36-1) + 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose (321156-96-1) → 4-nitrophenyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-1,3-dithio-β-D-glucopyranoside

Guidance literature:

With boron trifluoride diethyl etherate; In 1,2-dichloro-ethane; at 20 ℃; for 0.5h;

DOI:10.1016/S0008-6215(00)00218-4

Reference yield: 47.2%

4-cyanobenzenethiol (36801-01-1) + 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose (321156-96-1) → 4-cyanophenyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-1,6-dithio-β-D-glucopyranoside (321156-97-2)

Guidance literature:

With boron trifluoride diethyl etherate; In 1,2-dichloro-ethane; at 20 ℃; for 1.5h;

DOI:10.1016/S0008-6215(00)00218-4

upstream raw materials:

acetic anhydride

methyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-3-thio-α-D-glucopyranoside

Downstream raw materials:

4-cyanophenyl 3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-1,6-dithio-β-D-glucopyranoside

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 321156-96-1 1-O-acetyl-3,6-anhydro-2,4-di-O-(4-nitrobenzoyl)-6-thio-α-D-glucopyranose

Send

Send

Metric Ton KG G Pound L ML

Send

Send