Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2

Base Information

• Chemical Name: Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2
• CAS No.: 443959-25-9
• Molecular Formula: C₅₄H₄₄Cl₂N₁₂Pd₃
• Molecular Weight: 1251.19
• Mol file: 443959-25-9.mol

Synonyms:Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2

Chemical Property of Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2

There total 2 articles about Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-PdCl2(3-phenyl-pyrazole)2 (443959-27-1,144088-13-1) → Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2 (443959-25-9)

Guidance literature:

With (C₂H₅)3N; In not given; byproducts: HCl; stoich. amount of base added to Pd complex;

DOI:10.1039/b201301k

Reference yield:

3-phenylpyrazole (2458-26-6) → Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2 (443959-25-9)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: (C₂H₅)3N / not given

With (C₂H₅)3N; In methanol;

DOI:10.1039/b201301k

Reference yield: 50.0%

Pd3(μ-3-phenyl-pyrazolate)4(3-phenyl-pyrazole)2Cl2 (443959-25-9) → (Pd(μ-3-phenyl-pyrazolate)2)3 (443959-26-0)

Guidance literature:

With (C₂H₅)3N; In dichloromethane; addn. of a 0.072M soln. of NEt3 in CH2Cl2 (0.174 mmol) to soln. of Pd complex (0.087 mmol) in CH2Cl2, reaction time: 3 h; evapd. unde vac., residue washed with MeOH;

DOI:10.1039/b201301k

upstream raw materials:

cis-PdCl₂(3-phenyl-pyrazole)2

3-phenylpyrazole

Downstream raw materials:

(Pd(μ-3-phenyl-pyrazolate)2)3