Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

Base Information

Chemical Name:Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside
CAS No.:141936-81-4
Molecular Formula:C₄₃H₄₇NO₁₄
Molecular Weight:801.844
Hs Code.:

Synonyms:Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

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Chemical Property of Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

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Technology Process of Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

There total 1 articles about Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 70831-94-6
3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-D-glucopyranosyl bromide

: 141936-80-3
Allyl 3,6-di-O-benzyl-4-deoxy-α-D-lyxo-hexopyranoside

: 141936-81-4
Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

Guidance literature:: With 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; 1) -50 deg C, 15 min, 2) r.t., 2 h;
DOI:10.1016/0008-6215(92)84069-5

Reference yield:

: 141936-81-4
Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

: 141936-82-5
3,6-Di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α,β-D-lyxo-hexopyranosyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 1) (PPh₃)3RhCl, 1,6-diazabicyclo<2.2.2>octane, 2) HgO, HgCl₂ / 1) benzene, water, ethanol, reflux, 15 h, 2) r.t., 22 h

2: oxalyl chloride, DMF / CH₂Cl₂ / 2 h / Ambient temperature

With Wilkinson's catalyst; oxalyl dichloride; N,N-dimethyl-formamide; 1,2-diaza-bicyclo[2.2.2]octane; mercury dichloride; mercury(II) oxide; In dichloromethane;
DOI:10.1016/0008-6215(92)84069-5

Reference yield:

: 141936-81-4
Allyl 3,6-di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-lyxo-hexopyranoside

: 141936-86-9,141936-87-0
3,6-Di-O-benzyl-4-deoxy-2-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α,β-D-lyxo-hexopyranoside

Guidance literature:: With Wilkinson's catalyst; 1,2-diaza-bicyclo[2.2.2]octane; mercury dichloride; mercury(II) oxide; Yield given. Multistep reaction; 1) benzene, water, ethanol, reflux, 15 h, 2) r.t., 22 h;
DOI:10.1016/0008-6215(92)84069-5