methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside

Base Information

• Chemical Name: methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside
• CAS No.: 119824-71-4
• Molecular Formula: C₁₄H₁₈O₅
• Molecular Weight: 267.286
• Mol file: 119824-71-4.mol

Synonyms:methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside

Chemical Property of methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside

There total 4 articles about methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

methyl 4-O-benzoyl-3-bromo-3,6-dideoxy-β-D-gulopyranoside (56879-71-1) → methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside (119824-71-4)

Guidance literature:

With sodium borodeuteride; nickel dichloride; In ethanol; for 12h; Ambient temperature;

DOI:10.1016/0008-6215(90)84227-L

Reference yield:

D-Fucose (73-34-7,87-96-7,488-79-9,551-63-3,609-01-8,643-17-4,643-18-5,4164-09-4,6014-42-2,6155-36-8,6189-71-5,6696-41-9,6736-43-2,13224-93-6,22611-09-2,28161-49-1,28161-50-4,28161-52-6,45864-36-6,63814-64-2,71116-59-1,71116-61-5,72598-05-1,87936-88-7,87936-89-8,97466-79-0,116908-82-8,120442-60-6,123484-22-0,133576-32-6) → methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside (119824-71-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 5percent HCl

2: 56 percent / pyridine / 2 h / Heating

3: 77 percent / barium carbonate, N-bromosuccinimide / CCl₄ / 6 h / Heating

4: 66 percent / sodium borodeuteride, nickel chloride / ethanol / 12 h / Ambient temperature

With pyridine; hydrogenchloride; N-Bromosuccinimide; sodium borodeuteride; barium carbonate; nickel dichloride; In tetrachloromethane; ethanol;

DOI:10.1016/0008-6215(90)84227-L

Reference yield:

methyl 6-deoxy-α/β-D-galactopyranoside (129172-95-8) → methyl (3S)-<3-(2)H>-4-O-benzoyl-3,6-dideoxy-β-D-xylo-hexopyranoside (119824-71-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 56 percent / pyridine / 2 h / Heating

2: 77 percent / barium carbonate, N-bromosuccinimide / CCl₄ / 6 h / Heating

3: 66 percent / sodium borodeuteride, nickel chloride / ethanol / 12 h / Ambient temperature

With pyridine; N-Bromosuccinimide; sodium borodeuteride; barium carbonate; nickel dichloride; In tetrachloromethane; ethanol;

DOI:10.1016/0008-6215(90)84227-L

upstream raw materials:

methyl 4-O-benzoyl-3-bromo-3,6-dideoxy-β-D-gulopyranoside

D-Fucose

methyl 6-deoxy-α/β-D-galactopyranoside

methyl 3,4-O-benzylidene-6-deoxy-D-galactopyranoside

Downstream raw materials:

methyl (3S)-<3-(2)H>-2,4-di-O-(p-bromobenzoyl)-3,6-dideoxy-β-D-xylo-hexopyranoside