C₂₉H₁₉BrO

Base Information

• Chemical Name: C₂₉H₁₉BrO
• CAS No.: 1121545-05-8
• Molecular Formula: C₂₉H₁₉BrO
• Molecular Weight: 463.373
• Mol file: 1121545-05-8.mol

Synonyms:C₂₉H₁₉BrO

Chemical Property of C₂₉H₁₉BrO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₉H₁₉BrO

There total 5 articles about C₂₉H₁₉BrO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Bromobiphenyl (2052-07-5) + 9-bromo-7H-benzo[c]fluoren-7-one (1121545-04-7) → C29H19BrO (1121545-05-8)

Guidance literature:

2-Bromobiphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.16667h;

9-bromo-7H-benzo[c]fluoren-7-one; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere;

DOI:10.1039/c0jm00593b

Reference yield:

methyl 5-bromo-2-(naphthalene-1-yl)benzoate (1262281-86-6) → C29H19BrO (1121545-05-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium hydroxide / ethanol / 6 h / Reflux

1.2: 20 °C

2.1: methanesulfonic acid / 24 h / 30 °C

3.1: n-butyllithium / tetrahydrofuran; hexane / 1.17 h / -78 °C

3.2: 20 °C / Inert atmosphere

With n-butyllithium; methanesulfonic acid; sodium hydroxide; In tetrahydrofuran; ethanol; hexane;

DOI:10.1039/c0jm00593b

Reference yield:

5-bromo-2-(naphthalene-1-yl)benzoic acid (1262281-87-7) → C29H19BrO (1121545-05-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: methanesulfonic acid / 24 h / 30 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 1.17 h / -78 °C

2.2: 20 °C / Inert atmosphere

With n-butyllithium; methanesulfonic acid; In tetrahydrofuran; hexane;

DOI:10.1039/c0jm00593b

upstream raw materials:

methyl 5-bromo-2-(naphthalene-1-yl)benzoate

5-bromo-2-(naphthalene-1-yl)benzoic acid

2-Bromobiphenyl

9-bromo-7H-benzo[c]fluoren-7-one

Downstream raw materials:

9-(10-phenylanthracene-9-yl)spiro[benzo[c]fluorene-7,9'-fluorene]