C₅₂H₈₁ClO₁₃Si₃

Base Information

Chemical Name:C₅₂H₈₁ClO₁₃Si₃
CAS No.:1332271-37-0
Molecular Formula:C₅₂H₈₁ClO₁₃Si₃
Molecular Weight:1033.92
Hs Code.:

C<sub>52</sub>H<sub>81</sub>ClO<sub>13</sub>Si<sub>3</sub>

Synonyms:C₅₂H₈₁ClO₁₃Si₃

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Chemical Property of C₅₂H₈₁ClO₁₃Si₃

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Technology Process of C₅₂H₈₁ClO₁₃Si₃

There total 29 articles about C₅₂H₈₁ClO₁₃Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1332271-36-9
C₅₉H₈₇ClO₁₃Si₃

: 1332271-37-0
C₅₂H₈₁ClO₁₃Si₃

Guidance literature:: With 5%-palladium/activated carbon; hydrogen; In ethyl acetate; at 20 ℃; for 3.5h;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-25-6
C₃₇H₅₇ClO₈Si₂

: 1332271-37-0
C₅₂H₈₁ClO₁₃Si₃

Guidance literature:: Multi-step reaction with 14 steps

1.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

1.2: 0.5 h / -78 °C / Inert atmosphere

2.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

3.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

4.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

5.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

6.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

6.2: Inert atmosphere

7.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

8.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

9.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

10.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

11.1: 2,6-dimethylpyridine / dichloromethane / 0.37 h / 0 °C / Inert atmosphere

12.1: camphor-10-sulfonic acid / methanol; dichloromethane / 5 h / 0 °C / Inert atmosphere

13.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.33 h / 20 °C / Inert atmosphere

14.1: 5%-palladium/activated carbon; hydrogen / ethyl acetate / 3.5 h / 20 °C

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; 5%-palladium/activated carbon; camphor-10-sulfonic acid; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; hydrogen; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; dicyclohexyl-carbodiimide; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 4.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-63-2
C₃₁H₄₃ClO₇Si

: 1332271-37-0
C₅₂H₈₁ClO₁₃Si₃

Guidance literature:: Multi-step reaction with 15 steps

1.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

2.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -78 °C / Inert atmosphere

3.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

4.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

5.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

6.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

7.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

7.2: Inert atmosphere

8.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

9.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

10.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

11.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

12.1: 2,6-dimethylpyridine / dichloromethane / 0.37 h / 0 °C / Inert atmosphere

13.1: camphor-10-sulfonic acid / methanol; dichloromethane / 5 h / 0 °C / Inert atmosphere

14.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.33 h / 20 °C / Inert atmosphere

15.1: 5%-palladium/activated carbon; hydrogen / ethyl acetate / 3.5 h / 20 °C

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; 5%-palladium/activated carbon; camphor-10-sulfonic acid; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; hydrogen; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 5.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094