3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

Base Information

Chemical Name:3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester
CAS No.:83187-05-7
Molecular Formula:C₂₀H₂₂N₂O₆
Molecular Weight:386.404
Hs Code.:

Synonyms:3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

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Chemical Property of 3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

There total 15 articles about 3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 83187-02-4
<4.4.3>propell-12-en-11-ol

: 99-33-2
3,5-dinitrobenoyl chloride

: 83187-05-7
3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

Guidance literature:: DOI:10.1021/ja00347a046

Reference yield:

: 13950-46-4
bicyclo<4.4.0>deca-3-ene-1,6-dicarboxylic anhydride

: 83187-05-7
3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

Guidance literature:: Multi-step reaction with 15 steps

1: 98 percent / lithium aluminum hydride / tetrahydrofuran / -65 - 0 °C

2: 72 percent / dimethylformamide; dimethylsulfoxide / 144 h / Heating

3: 95 percent / aq. sodium hydroxide / 48 h / Heating

4: 97 percent / acetic anhydride / 12 h / Heating

5: 97 percent / lithium aluminum hydride / tetrahydrofuran / -65 °C

6: 84 percent / dimethylformamide; dimethylsulfoxide / 144 h / Heating

7: 87 percent / aq. sodium hydroxide / 48 h / Heating

8: hydrogen / 5percent palladium/charcoal / ethanol / 15 h / 2585.7 Torr

9: 96 percent / diethyl ether; dioxane

10: 89 percent / sodium hydride / tetrahydrofuran / 1.) room temperature, 1 h, 2.) reflux, 22 h

11: 96 percent / aq. sodium chloride / dimethylformamide / Heating

12: 440 mg / pyridinium hydrobromide perbromide / acetic acid / 1.) 10 deg C, 3 h, 2.) room temperature, 13 h

13: 63 percent / lithium chloride, lithium carbonate / dimethylformamide / 120 h / Heating

14: 89 percent / diisobutylaluminum hydride / benzene; hexane / 2.5 h / 5 °C

15: 51 percent

With sodium hydroxide; lithium aluminium tetrahydride; hydrogen; pyridinium hydrobromide perbromide; acetic anhydride; lithium carbonate; sodium hydride; diisobutylaluminium hydride; lithium chloride; sodium chloride; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; hexane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; benzene;
DOI:10.1021/ja00347a046

Reference yield:

: 85067-45-4
cis-9-(carboxymethyl)-Δ²-octalin-10-carboxylic acid

: 83187-05-7
3,5-Dinitro-benzoic acid octahydro-4a,8a-propeno-naphthalen-9-yl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 97 percent / acetic anhydride / 12 h / Heating

2: 97 percent / lithium aluminum hydride / tetrahydrofuran / -65 °C

3: 84 percent / dimethylformamide; dimethylsulfoxide / 144 h / Heating

4: 87 percent / aq. sodium hydroxide / 48 h / Heating

5: hydrogen / 5percent palladium/charcoal / ethanol / 15 h / 2585.7 Torr

6: 96 percent / diethyl ether; dioxane

7: 89 percent / sodium hydride / tetrahydrofuran / 1.) room temperature, 1 h, 2.) reflux, 22 h

8: 96 percent / aq. sodium chloride / dimethylformamide / Heating

9: 440 mg / pyridinium hydrobromide perbromide / acetic acid / 1.) 10 deg C, 3 h, 2.) room temperature, 13 h

10: 63 percent / lithium chloride, lithium carbonate / dimethylformamide / 120 h / Heating

11: 89 percent / diisobutylaluminum hydride / benzene; hexane / 2.5 h / 5 °C

12: 51 percent

With sodium hydroxide; lithium aluminium tetrahydride; hydrogen; pyridinium hydrobromide perbromide; acetic anhydride; lithium carbonate; sodium hydride; diisobutylaluminium hydride; lithium chloride; sodium chloride; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; hexane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; benzene;
DOI:10.1021/ja00347a046