C₁₆H₁₇N₃OSi

Base Information

• Chemical Name: C₁₆H₁₇N₃OSi
• CAS No.: 1450667-14-7
• Molecular Formula: C₁₆H₁₇N₃OSi
• Molecular Weight: 295.416
• Mol file: 1450667-14-7.mol

Synonyms:C₁₆H₁₇N₃OSi

Chemical Property of C₁₆H₁₇N₃OSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of C₁₆H₁₇N₃OSi

There total 4 articles about C₁₆H₁₇N₃OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C19H25N3OSi2 (1450667-15-8) → C16H17N3OSi (1450667-14-7)

Guidance literature:

With camphor-10-sulfonic acid; In methanol; for 1h;

DOI:10.1016/j.tetlet.2013.07.001

Reference yield:

trimethylsilylazide (4648-54-8) + C16H16OSi → C16H17N3OSi (1450667-14-7) + C19H25N3OSi2 (1450667-15-8) + C16H17N3OSi

Guidance literature:

C₁₆H₁₆OSi; With (1R,2R) N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride; In diethyl ether; at 20 ℃; for 0.25h;

trimethylsilylazide; In diethyl ether; Overall yield = 59 %; enantioselective reaction;

DOI:10.1016/j.tetlet.2013.07.001

Reference yield:

C16H17ClOSi (1450667-16-9) → C16H17N3OSi (1450667-14-7)

Guidance literature:

Multi-step reaction with 2 steps

1: (1R,2R) N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride / diethyl ether / 0.25 h / -70 °C

2: (1R,2R) N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride / diethyl ether / 0.25 h / 20 °C

With (1R,2R) N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediamino chromium(III) chloride; In diethyl ether;

DOI:10.1016/j.tetlet.2013.07.001

upstream raw materials:

trimethylsilylazide

C₁₉H₂₅N₃OSi₂

C₁₆H₁₇ClOSi

Downstream raw materials:

(R)-(+)-3,4-dihydroxy-1-butene

C₂₃H₂₃NO₂Si

C₁₆H₁₉NOSi

C₂₂H₂₇N₃OSi