Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

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Chemical Name:Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester
CAS No.:1053714-70-7
Molecular Formula:C₂₅H₃₂F₃NO₇S₂
Molecular Weight:579.659
Hs Code.:

Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

Synonyms:Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

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Chemical Property of Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

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Technology Process of Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

There total 24 articles about Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: 646994-49-2
(R)-4-[(2R,4S,6R)-4-Hydroxy-2-methoxy-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-2-yl]-3-(4-methoxy-benzyl)-thiazolidin-2-one

: 1053714-70-7
Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

Guidance literature:: With pyridine; In dichloromethane; at -10 ℃;
DOI:10.1002/anie.200352413

Reference yield:

: 101860-50-8
(-)-3-(4-methoxybenzyl)-2-oxo-thiazolidine-4-carboxylic acid ethyl ester

: 1053714-70-7
Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: nBuLi / hexane; tetrahydrofuran / 0.33 h / -78 °C

1.2: 60 percent / hexane; tetrahydrofuran / 0.5 h

2.1: 75 percent / Ba(OH)2*8H₂O / tetrahydrofuran; H₂O / 3 h

3.1: 57 percent / aq. HCl / tetrahydrofuran / 20 °C

4.1: 92 percent / camphor-10-sulfonic acid / 20 °C

5.1: pyridine / CH₂Cl₂ / 1 h / -20 °C

With pyridine; hydrogenchloride; barium dihydroxide; n-butyllithium; camphor-10-sulfonic acid; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1002/chem.200601135

Reference yield:

: 646994-44-7
(3R,6S)-3-(tert-Butyl-dimethyl-silanyloxy)-6-methyl-non-7-ynal

: 1053714-70-7
Trifluoro-methanesulfonic acid (2R,4S,6R)-2-methoxy-2-[(R)-3-(4-methoxy-benzyl)-2-oxo-thiazolidin-4-yl]-6-((S)-3-methyl-hex-4-ynyl)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / Ba(OH)2*8H₂O / tetrahydrofuran; H₂O / 3 h

2: 57 percent / aq. HCl / tetrahydrofuran / 20 °C

3: 92 percent / camphor-10-sulfonic acid / 20 °C

4: pyridine / CH₂Cl₂ / 1 h / -20 °C

With pyridine; hydrogenchloride; barium dihydroxide; camphor-10-sulfonic acid; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/chem.200601135