2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

Base Information

Chemical Name:2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside
CAS No.:115946-00-4
Molecular Formula:C₆₆H₇₂Cl₃N₃O₁₆
Molecular Weight:1269.67
Hs Code.:

2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

Synonyms:2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

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Chemical Property of 2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

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Technology Process of 2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

There total 14 articles about 2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.2%

: 115945-94-3
2,2,2-trichloroethyl 3,4-di-O-benzyl-2-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-α-L-rhamnopyranoside

: 115945-99-8
4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-mannopyranosyl bromide

: 115946-00-4
2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

: 2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: With 4 A molecular sieve; In dichloromethane; benzene; for 1h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90854-1

Reference yield:

: 116003-77-1
2-azido-2-deoxy-4,6-O-(phenylmethylene)methyl-α-D-altropyranoside

: 115946-00-4
2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 8 steps

1: 6.7 g / NaH / dimethylformamide / 1.) O deg C, 30 min; 2.) -40 deg C, 2 min

2: 63.1 percent / toluene / 2 h / Heating

3: 93 percent / M sodium methoxide / methanol / 4 h / Ambient temperature

4: 99 percent / NaH / dimethylformamide / 1 h

5: 91.3 percent / 2M hydrochloric acid / acetone / 1 h / Heating

6: 2.1 g / aq. H₂SO₄ / 17 h / -20 °C

7: 76 mg / titanium tetrabromide / CH₂Cl₂; ethyl acetate / 50 h / Ambient temperature

8: 32.7 percent / molecular sieves 4 A / benzene; CH₂Cl₂ / 1 h / Ambient temperature

With hydrogenchloride; 4 A molecular sieve; sodium methylate; titanium(IV) bromide; sodium hydride; In methanol; dichloromethane; sulfuric acid; ethyl acetate; N,N-dimethyl-formamide; acetone; toluene; benzene;
DOI:10.1016/S0008-6215(00)90854-1

Reference yield:

: 61236-94-0
4-O-acetyl-2,3,6-tri-O-benzyl-α-D-glucopyranosyl chloride

: 115946-00-4
2,2,2-trichloroethyl 2-O-<2,3-tri-O-benzyl-4-O-(4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-mannopyranosyl)-α-D-glucopyranosyl>-3,4-di-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 28.4 percent / sym-collidine/silver perchlorate / benzene; diethyl ether / 1 h

2: 85.3 percent / M sodium methoxide / methanol / 4 h / Ambient temperature

3: 32.7 percent / molecular sieves 4 A / benzene; CH₂Cl₂ / 1 h / Ambient temperature

With 2,4,6-trimethyl-pyridine; 4 A molecular sieve; sodium methylate; silver perchlorate; In methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1016/S0008-6215(00)90854-1