HNiSC₆H₄CH₃(P(C₆H₁₁)3)2

Base Information

• Chemical Name: HNiSC₆H₄CH₃(P(C₆H₁₁)3)2
• CAS No.: 107406-69-9
• Molecular Formula: C₄₃H₇₄NiP₂S
• Molecular Weight: 743.764

Synonyms:HNiSC₆H₄CH₃(P(C₆H₁₁)3)2

Chemical Property of HNiSC₆H₄CH₃(P(C₆H₁₁)3)2

Chemical Property:

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Technology Process of HNiSC₆H₄CH₃(P(C₆H₁₁)3)2

There total 2 articles about HNiSC₆H₄CH₃(P(C₆H₁₁)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

[Ni(PCy3)2]2(N2) + para-thiocresol (106-45-6) → HNiSC6H4CH3(P(C6H11)3)2 (107406-69-9)

Guidance literature:

In diethyl ether; toluene; (Ar); to Ar-purged soln. of Ni complex in toluene was added CH3C6H4SH soln. in ether, mixt. was warmed up to room temp. under stirring, then cooled to -78°C; mixt. was filtered, washed with ether and dried in vac.;

Reference yield:

[Ni(PCy3)2]2(N2) + para-thiocresol (106-45-6) → HNiSC6H4CH3(P(C6H11)3)2 (107406-69-9)

Guidance literature:

With hydrogen sulfide; In not given; byproducts: N2; according to: P. W. Jolly, Angew. Chem. 80 (1968) 705; smooth react. atroom temp.;;

Reference yield: 96.0%

HNiSC6H4CH3(P(C6H11)3)2 (107406-69-9) → trans-hydridoiodobis(tricyclohexylphosphine)nickel(II) (30376-82-0)

Guidance literature:

With CH₃I; In benzene-d6; byproducts: CH4, C2H6; to soln. of Ni hydride was added MeI (1:1 mol); products were identified by (1)H-NMR;

upstream raw materials:

para-thiocresol

Downstream raw materials:

trans-hydridoiodobis(tricyclohexylphosphine)nickel(II)

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