gallium(3+) perchlorate

Base Information

• Chemical Name: gallium(3+) perchlorate
• CAS No.: 19854-31-0
• Molecular Formula: ClH O4 . 1/3 Ga
• Molecular Weight: 368.0748
• Mol file: 19854-31-0.mol

Synonyms:Galliumperchlorate (6CI,7CI); Gallium perchlorate (Ga(ClO4)3); Gallium triperchlorate;Perchloric acid gallium(3+) salt

Chemical Property of gallium(3+) perchlorate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 83.50000
• Density: g/cm³
• LogP: 0.10670

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of gallium(3+) perchlorate

There total 2 articles about gallium(3+) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(CH3)2Ga(H2O)2(1+)*ClO4(1-)=((CH3)2Ga(H2O)2)ClO4 → gallium(III) perchlorate hydrate (19854-31-0) + methane (34557-54-5,27936-85-2)

Guidance literature:

With perchloric acid; water; In water; 0.0164 or 0.0179 M HClO4, room temp., 150 d; ca. 36% of the available methyl groups were converted to CH4; volumetric detn. of evolved CH4 and (1)H NMR monitoring of Me2GaClO4/added acetone ratio;

DOI:10.1021/om00147a008

Reference yield:

gallium(III) oxide + perchloric acid (7601-90-3) → gallium(III) perchlorate hydrate (19854-31-0)

Guidance literature:

In water; Ga2O3 was slurried in water and concd. HClO4 was added dropwise; the mixt. was refluxed for 2 h; after boiling off some of the water the soln. was evapd. in a desiccator;

DOI:10.1039/b212140a

upstream raw materials:

perchloric acid

Refernces

• 1、 Davidian,Pestova,Starova,Gurzhii,Myund,Khripun. "X-ray diffraction study of isomorphous crystal nonahydrates of aluminum, gallium, and scandium perchlorates". . p. 621 - 625. Retrieved 2012.