Technology Process of C35H56O7Si
There total 11 articles about C35H56O7Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
Dess-Martin periodane;
In
dichloromethane;
DOI:10.1021/ja073952e
- Guidance literature:
-
Multi-step reaction with 9 steps
1: 74 percent / [RuCl2(=CHPh)(PCy3)(SIMes)] / CH2Cl2 / 40 °C
2: DIBALH / CH2Cl2 / -78 °C
3: toluene / 80 °C
4: imidazole / CH2Cl2
5: DIBALH / CH2Cl2 / -78 °C
6: L-(+)-diethyl tartrate; Ti(i-PrO)4; TBHP / molecular sieves 4 Angstroem / CH2Cl2 / -20 °C
7: SO3*pyridine; DMSO; Et3N / CH2Cl2 / -78 - 0 °C
8: 27 percent / LDA / diethyl ether / -78 °C
9: 97 percent / Dess-Martin periodinane / CH2Cl2
With
1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; pyridine-SO3 complex; diethyl (2R,3R)-tartrate; diisobutylaluminium hydride; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide;
4 A molecular sieve;
In
diethyl ether; dichloromethane; toluene;
3: Wittig reaction / 6: Sharpless asymmetric epoxidation;
DOI:10.1021/ja073952e
- Guidance literature:
-
Multi-step reaction with 6 steps
1: imidazole / CH2Cl2
2: DIBALH / CH2Cl2 / -78 °C
3: L-(+)-diethyl tartrate; Ti(i-PrO)4; TBHP / molecular sieves 4 Angstroem / CH2Cl2 / -20 °C
4: SO3*pyridine; DMSO; Et3N / CH2Cl2 / -78 - 0 °C
5: 27 percent / LDA / diethyl ether / -78 °C
6: 97 percent / Dess-Martin periodinane / CH2Cl2
With
1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; pyridine-SO3 complex; diethyl (2R,3R)-tartrate; diisobutylaluminium hydride; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide;
4 A molecular sieve;
In
diethyl ether; dichloromethane;
3: Sharpless asymmetric epoxidation;
DOI:10.1021/ja073952e
