2,2,3,3-Tetrafluoropropyl trifluoroacetate

Base Information

• Chemical Name: 2,2,3,3-Tetrafluoropropyl trifluoroacetate
• CAS No.: 107551-72-4
• Molecular Formula: C₅H₃F₇O₂
• Molecular Weight: 228.066
• Hs Code.: 2915900090
• European Community (EC) Number: 822-785-6
• DSSTox Substance ID: DTXSID50380243
• Wikidata: Q81985853
• Mol file: 107551-72-4.mol

Synonyms:2,2,3,3-Tetrafluoropropyl trifluoroacetate;107551-72-4;2,2,3,3-tetrafluoropropyl 2,2,2-trifluoroacetate;SCHEMBL13280672;DTXSID50380243;QWXXHRSQCJGYQR-UHFFFAOYSA-N;MFCD00516928;AKOS015852764

Chemical Property of 2,2,3,3-Tetrafluoropropyl trifluoroacetate

Chemical Property:

• Vapor Pressure: 51.5mmHg at 25°C
• Refractive Index: 1.293
• Boiling Point: 90-93°C
• Flash Point: 10.7°C
• PSA: 26.30000
• Density: 1.489g/cm³
• LogP: 1.99230
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 4
• Exact Mass: 228.00212647
• Heavy Atom Count: 14
• Complexity: 209

Purity/Quality:

98%min ^*data from raw suppliers

2,2,3,3-TetrafluoropropylTrifluoroacetate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(F)F)(F)F)OC(=O)C(F)(F)F

Technology Process of 2,2,3,3-Tetrafluoropropyl trifluoroacetate

There total 4 articles about 2,2,3,3-Tetrafluoropropyl trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

C12H12F16O4Te (85878-21-3) + trifluoroacetic anhydride (407-25-0) → trifluoroethanoic acid 2,2,3,3-tetrafluoropropyl ester (107551-72-4) + C11H9F15O5Te (107905-27-1)

Guidance literature:

at 20 ℃; for 2h; Yields of byproduct given; ether as solvent;;

Reference yield: 73.0%

C12H12F16O4Te (85878-21-3) + trifluoroacetic anhydride (407-25-0) → trifluoroethanoic acid 2,2,3,3-tetrafluoropropyl ester (107551-72-4)

Guidance literature:

at 80 - 120 ℃;

Reference yield: 45.0%

2,2,2-Trifluoro-acetimidic acid 2,2,3,3-tetrafluoro-propyl ester → trifluoroethanoic acid 2,2,3,3-tetrafluoropropyl ester (107551-72-4) + 1,1,3-trihydroperfluoropropyl ester of N-fluoriminotrifluoroacetic acid

Guidance literature:

With nickel; fluorine; at -5 - 0 ℃;

DOI:10.1007/BF00950032

upstream raw materials:

C₁₀H₆F₁₄O₆Te

C₁₂H₁₂F₁₆O₄Te

trifluoroacetic anhydride

Refernces

• 1、 Stukalo, E. A.,Yur'eva, E. M.,Markovskii, L. N.. "REACTION OF TETRAKIS(POLYFLUOROALKOXY)TELLURANES WITH CARBOXYLIC AND DICARBOXYLIC ACID ANHYDRIDES". . p. 675 - 681. Retrieved 2007/10/02.