DL-Glycerin-1-n-hexylether

Base Information

• Chemical Name: DL-Glycerin-1-n-hexylether
• CAS No.: 106972-45-6
• Molecular Formula: C9H20O3
• Molecular Weight: 0
• Mol file: 106972-45-6.mol

Synonyms:DL-Glycerin-1-n-hexylether

Chemical Property of DL-Glycerin-1-n-hexylether

Chemical Property:

• Boiling Point: 92 - 93 °C (1 mmHg)
• PSA: 49.69000
• LogP: 0.93650

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DL-Glycerin-1-n-hexylether

There total 16 articles about DL-Glycerin-1-n-hexylether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2,3-dihydroxypropyl hexanoate (502-53-4) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → hexyl glycerol (106972-45-6) + 2-O-hexylglycerol (100078-38-4)

Guidance literature:

With 5%-palladium/activated carbon; hydrogen; at 120 ℃; for 16h; under 37503.8 Torr; regioselective reaction; Autoclave;

DOI:10.1039/c3gc36907b

Reference yield: 73.0%

methyl hexanoate (106-70-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → hexyl glycerol (106972-45-6) + 2-O-hexylglycerol (100078-38-4)

Guidance literature:

With 5%-palladium/activated carbon; camphor-10-sulfonic acid; hydrogen; at 120 ℃; for 16h; under 37503.8 Torr; regioselective reaction; Autoclave;

DOI:10.1039/c3gc36907b

Reference yield: 72.0%

glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) + hexanoic acid (142-62-1) → hexyl glycerol (106972-45-6)

Guidance literature:

With palladium on activated charcoal; hydrogen; at 120 ℃; for 16h; under 37503.8 Torr; Autoclave; Inert atmosphere;

DOI:10.1002/cssc.201200447

upstream raw materials:

3-hex-1-en-t-yloxy-propane-1,2-diol

3-monochloro-1,2-propanediol

hexan-1-ol

1-bromo-hexane

Downstream raw materials:

2-Benzyloxy-3-hexyloxy-propan-1-ol

Phosphoric acid 2-benzyloxy-3-hexyloxy-propyl ester 2-bromo-ethyl ester

C₂₁H₃₈NO₆P

C₃₅H₄₀O₃