(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

Base Information

Chemical Name:(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene
CAS No.:137871-75-1
Molecular Formula:C₂₂H₃₂O₆SSi
Molecular Weight:452.644
Hs Code.:

Synonyms:(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

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Chemical Property of (E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

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Technology Process of (E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

There total 5 articles about (E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 137871-74-0
2-((E)-5-(phenylsulfonyl)-4-pentenyl)-2-(2-((methoxycarbonyl)oxy)-3-((trimethylsilyl)methyl)-3-buten-2-yl)-1,3-dithiane

: 137871-75-1
(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

Guidance literature:: With N-chloro-succinimide; silver nitrate; In water; acetonitrile; for 0.166667h;
DOI:10.1021/jo00028a052

Reference yield:

: 56069-39-7
diethyl phenylsulfonylmethylphosphonate

: 137871-75-1
(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) sodium bis(trimethylsilyl)amide / 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 45 min

2: 44 percent / NCS, silver nitrate / acetonitrile; H₂O / 0.17 h

With N-chloro-succinimide; sodium hexamethyldisilazane; silver nitrate; In water; acetonitrile;
DOI:10.1021/jo00028a052

Reference yield:

: 137871-71-7
1-[2-(4,4-Dimethoxy-butyl)-[1,3]dithian-2-yl]-ethanone

: 137871-75-1
(E)-1-(phenylsulfonyl)-6-oxo-7-((methoxycarbonyl)oxy)-7-methyl-8-((trimethylsilyl)methyl)-1,8-nonadiene

Guidance literature:: Multi-step reaction with 4 steps

2: 96 percent / 1 N H₂SO₄ / tetrahydrofuran / 4 h / 40 °C

3: 1.) sodium bis(trimethylsilyl)amide / 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 45 min

4: 44 percent / NCS, silver nitrate / acetonitrile; H₂O / 0.17 h

With N-chloro-succinimide; sulfuric acid; sodium hexamethyldisilazane; silver nitrate; In tetrahydrofuran; water; acetonitrile;
DOI:10.1021/jo00028a052