Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonyl chloride (9CI)

Base Information

• Chemical Name: Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonyl chloride (9CI)
• CAS No.: 106817-62-3
• Molecular Formula: C₁₂H₉ClO
• Molecular Weight: 204.656
• Hs Code.: 2916209090
• Mol file: 106817-62-3.mol

Synonyms:Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonylchloride, (?à)-

Chemical Property of Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonyl chloride (9CI)

Chemical Property:

• PSA: 17.07000
• LogP: 3.09420

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonyl chloride (9CI)

There total 1 articles about Bicyclo[4.4.1]undeca-1,3,5,7,9-pentaene-2-carbonyl chloride (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,6-Methano-<10>annulen-2-carbonsaeure (5873-56-3,34029-50-0,34029-51-1) → Bicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2-carbonsaeure-chlorid (106817-62-3)

Guidance literature:

With thionyl chloride;

Reference yield:

Bicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2-carbonsaeure-chlorid (106817-62-3) → 10-Benzoyl-N,N-diethylbicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2-carbonsaeureamid

Guidance literature:

Multi-step reaction with 3 steps

1: 96 percent / diethyl ether / 1 h / Ambient temperature

2: 2.5 M BuLi, TMEDA / tetrahydrofuran; hexane / 1 h / -78 °C

3: 47.5 percent / tetrahydrofuran / 16 h / Ambient temperature

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1002/hlca.19860690531

Reference yield:

Bicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2-carbonsaeure-chlorid (106817-62-3) → Bicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2,10-dicarbonsaeure-anhydrid (6074-92-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 96 percent / diethyl ether / 1 h / Ambient temperature

2: 2.5 M BuLi, TMEDA / tetrahydrofuran; hexane / 1 h / -78 °C

3: tetrahydrofuran / 0.25 h / -78 °C

4: acetonitrile / 1 h / Heating

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; diethyl ether; hexane; acetonitrile;

DOI:10.1002/hlca.19860690531

upstream raw materials:

1,6-Methano-<10>annulen-2-carbonsaeure

Downstream raw materials:

Bicyclo<4.4.1>undeca-1,3,5,7,9-pentaen-2,10-dicarbonsaeure-anhydrid