C₆₃H₉₆BClO₁₁Si

Base Information

Chemical Name:C₆₃H₉₆BClO₁₁Si
CAS No.:392692-65-8
Molecular Formula:C₆₃H₉₆BClO₁₁Si
Molecular Weight:1103.8
Hs Code.:

C<sub>63</sub>H<sub>96</sub>BClO<sub>11</sub>Si

Synonyms:C₆₃H₉₆BClO₁₁Si

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Chemical Property of C₆₃H₉₆BClO₁₁Si

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Technology Process of C₆₃H₉₆BClO₁₁Si

There total 54 articles about C₆₃H₉₆BClO₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 862509-84-0
(4R,5R,6R)-5-benzyloxy-4-[1-hydroxy-prop-2-(R)-yl]-2,2,6-trimethyl-1,3-dioxane

: 392692-65-8
C₆₃H₉₆BClO₁₁Si

Guidance literature:: Multi-step reaction with 15 steps

1.1: Dess-Martin periodinane / CH₂Cl₂ / 3 h / 20 °C

2.1: LiCl; i-PrNEt₂ / acetonitrile / 16 h / 20 °C

3.1: enriched AD-mix-β; MeSO3NH2 / 2-methyl-propan-2-ol; H2O / 8 h / 20 °C

4.1: H₂; NaHCO₃ / Pd(OH)2/C / methanol / 20 h / 20 °C

5.1: Ph₃CBF₄ / tetrahydrofuran / 2 h / 0 °C

6.1: DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

6.2: Ba(OH)2 / tetrahydrofuran; H₂O / 16 h / 20 °C

7.1: AcOH / tetrahydrofuran; H₂O / 48 h / 20 °C

7.2: 86 percent / KOH / methanol / 24 h / 20 °C

8.1: toluene / 2 h / 120 °C

9.1: tetrapropylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 20 °C

10.1: Et₃N / diethyl ether / 2.5 h / -78 °C

11.1: diethyl ether / 16 h / -78 - -20 °C

11.2: H₂O₂ / methanol; H₂O / 2 h / 0 - 20 °C / pH 7

12.1: PPTS / methanol / 1 h / 20 °C

13.1: imidazole; Et₃N / dimethylformamide / 16 h / 20 °C

14.1: OsO₄; H₂O; Me₃NO / acetone / 16 h / 20 °C

14.2: Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.67 h / 0 °C

15.1: Et₃N / diethyl ether / 1.5 h / -78 - -40 °C

With 1H-imidazole; osmium(VIII) oxide; tetrapropylammonium perruthennate; sulfamic acid methyl ester; N,N-diethyl-N-isopropylamine; trimethylamine-N-oxide; enriched AD-mix-β; water; hydrogen; trityl tetrafluoroborate; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 4-methylmorpholine N-oxide; triethylamine; lithium chloride; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Dess-Martin oxidation / 2.1: Horner-Wadsworth-Emmons olefination / 3.1: Sharpless dihydroxylation / 6.2: Horner-Wadsworth-Emmons olefination / 7.1: hetero-Michael cyclization / 8.1: Petasis methylenation;
DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H

Reference yield:

: 194934-58-2
(S)-2-[5-(R)-benzyloxy-2,2,6-(6R)-trimethyl-1,3-dioxan-4-(R)-yl]-propionaldehyde

: 392692-65-8
C₆₃H₉₆BClO₁₁Si

Guidance literature:: Multi-step reaction with 14 steps

1.1: LiCl; i-PrNEt₂ / acetonitrile / 16 h / 20 °C

2.1: enriched AD-mix-β; MeSO3NH2 / 2-methyl-propan-2-ol; H2O / 8 h / 20 °C

3.1: H₂; NaHCO₃ / Pd(OH)2/C / methanol / 20 h / 20 °C

4.1: Ph₃CBF₄ / tetrahydrofuran / 2 h / 0 °C

5.1: DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

5.2: Ba(OH)2 / tetrahydrofuran; H₂O / 16 h / 20 °C

6.1: AcOH / tetrahydrofuran; H₂O / 48 h / 20 °C

6.2: 86 percent / KOH / methanol / 24 h / 20 °C

7.1: toluene / 2 h / 120 °C

8.1: tetrapropylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 20 °C

9.1: Et₃N / diethyl ether / 2.5 h / -78 °C

10.1: diethyl ether / 16 h / -78 - -20 °C

10.2: H₂O₂ / methanol; H₂O / 2 h / 0 - 20 °C / pH 7

11.1: PPTS / methanol / 1 h / 20 °C

12.1: imidazole; Et₃N / dimethylformamide / 16 h / 20 °C

13.1: OsO₄; H₂O; Me₃NO / acetone / 16 h / 20 °C

13.2: Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.67 h / 0 °C

14.1: Et₃N / diethyl ether / 1.5 h / -78 - -40 °C

With 1H-imidazole; osmium(VIII) oxide; tetrapropylammonium perruthennate; sulfamic acid methyl ester; N,N-diethyl-N-isopropylamine; trimethylamine-N-oxide; enriched AD-mix-β; water; hydrogen; trityl tetrafluoroborate; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; acetic acid; 4-methylmorpholine N-oxide; triethylamine; lithium chloride; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 1.1: Horner-Wadsworth-Emmons olefination / 2.1: Sharpless dihydroxylation / 5.2: Horner-Wadsworth-Emmons olefination / 6.1: hetero-Michael cyclization / 7.1: Petasis methylenation;
DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H

Reference yield:

: (R)-1-Benzyloxy-4-(4-methoxy-benzyloxy)-3-methyl-butan-2-one

: 392692-65-8
C₆₃H₉₆BClO₁₁Si

Guidance literature:: Multi-step reaction with 19 steps

1.1: cHex₂BCl; Et₃N / diethyl ether / 2 h / -78 °C

1.2: 16 h / -78 - -20 °C

1.3: 93 percent / H₂O₂ / methanol; H₂O / 3 h / 0 - 20 °C / pH 7

2.1: Me₄NBH(OAc)3 / acetonitrile; acetic acid / 60 h / 4 °C

3.1: PPTS / CH₂Cl₂ / 16 h / 20 °C

4.1: DDQ / CH₂Cl₂ / 1.5 h / 0 °C / pH 7

5.1: Dess-Martin periodinane / CH₂Cl₂ / 3 h / 20 °C

6.1: LiCl; i-PrNEt₂ / acetonitrile / 16 h / 20 °C

7.1: enriched AD-mix-β; MeSO3NH2 / 2-methyl-propan-2-ol; H2O / 8 h / 20 °C

8.1: H₂; NaHCO₃ / Pd(OH)2/C / methanol / 20 h / 20 °C

9.1: Ph₃CBF₄ / tetrahydrofuran / 2 h / 0 °C

10.1: DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

10.2: Ba(OH)2 / tetrahydrofuran; H₂O / 16 h / 20 °C

11.1: AcOH / tetrahydrofuran; H₂O / 48 h / 20 °C

11.2: 86 percent / KOH / methanol / 24 h / 20 °C

12.1: toluene / 2 h / 120 °C

13.1: tetrapropylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 20 °C

14.1: Et₃N / diethyl ether / 2.5 h / -78 °C

15.1: diethyl ether / 16 h / -78 - -20 °C

15.2: H₂O₂ / methanol; H₂O / 2 h / 0 - 20 °C / pH 7

16.1: PPTS / methanol / 1 h / 20 °C

17.1: imidazole; Et₃N / dimethylformamide / 16 h / 20 °C

18.1: OsO₄; H₂O; Me₃NO / acetone / 16 h / 20 °C

18.2: Pb(OAc)4; Na₂CO₃ / CH₂Cl₂ / 0.67 h / 0 °C

19.1: Et₃N / diethyl ether / 1.5 h / -78 - -40 °C

With 1H-imidazole; osmium(VIII) oxide; tetrapropylammonium perruthennate; sulfamic acid methyl ester; N,N-diethyl-N-isopropylamine; trimethylamine-N-oxide; enriched AD-mix-β; dicyclohexylboron chloride; water; hydrogen; trityl tetrafluoroborate; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; tetramethylammonium triacetoxyborohydride; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol; 5.1: Dess-Martin oxidation / 6.1: Horner-Wadsworth-Emmons olefination / 7.1: Sharpless dihydroxylation / 10.2: Horner-Wadsworth-Emmons olefination / 11.1: hetero-Michael cyclization / 12.1: Petasis methylenation;
DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H