2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

Base Information

Chemical Name:2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>
CAS No.:136737-93-4
Molecular Formula:C₃₈H₄₂O₆
Molecular Weight:594.748
Hs Code.:

Synonyms:2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

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Chemical Property of 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

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Technology Process of 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

There total 2 articles about 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 136737-92-3
allyl 3,4,5,7-tetra-O-benzyl-1-deoxy-1-iodo-α-D-gluco-2-heptulopyranoside

: 136737-93-4
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 85 ℃; for 1h;
DOI:10.1016/0008-6215(92)84174-Q

Reference yield:

: 133697-34-4,97321-70-5
2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-hept-1-enitol

: 136737-93-4
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

Guidance literature:: Multi-step reaction with 2 steps

1: 1) N-iodosuccinimide / 1) CH₂Cl₂, -78 deg C, 1 h, 2) -78 deg C, 20 min

2: 77 percent / Bu₃SnH, AIBN / benzene / 1 h / 85 °C

With N-iodo-succinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene;
DOI:10.1016/0008-6215(92)84174-Q

Reference yield: 60.0%

: 136737-93-4
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosylspiro-2'-<(4'S)-4'-methyltetrahydrofuran>

: 136737-94-5
4,8-anhydro-5,6,7,9-tetra-O-benzyl-2,3-dideoxy-2-C-methyl-D-erythro-L-galacto-nonitol

Guidance literature:: With triethylsilane; boron trifluoride diethyl etherate; trifluoroacetic acid; for 0.5h; Ambient temperature;
DOI:10.1016/0008-6215(92)84174-Q