(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

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Chemical Name:(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate
CAS No.:82338-51-0
Molecular Formula:C₄₀H₄₁ClP₄Ru
Molecular Weight:782.184
Hs Code.:

Synonyms:(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

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Chemical Property of (+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

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Technology Process of (+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

There total 2 articles about (+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 16853-85-3
lithium aluminium tetrahydride

: 82373-48-6
(+)589-λ-anti-cis-C2-dichlorobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

: 82338-51-0
(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

Guidance literature:: In tetrahydrofuran; dichloromethane; soln. of Ru complex in THF stirred with excess LiAlH4 for 20 min, filtered, evapd. to dryness, residue dissolved in CH2Cl2, added HCl; org. layer sepd., dried, evapd., residue recrystd. from benzene;

Reference yield: 61.0%

: 82338-48-5
(+)589-trans-dichlorobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

: 97-93-8
triethylaluminum

: 82338-51-0
(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

: 555-75-9
aluminum ethoxide

Guidance literature:: With C₂H₅OH; HCl; In further solvent(s); under N2, Ru complex added to Et3Al diluted with CH2Cl2, cooled to -78°C, ethanol slowly added, evapd. at 50°C, residue dissolvedin CH2Cl2, cooled to -78°C, treated with HCl; org. layer sepd., dried at -78°C, solvent evapd., recrystd. frombenzene, elem. anal.;

Reference yield: 80.0%

: ammonium hexafluorophosphate

: 82338-51-0
(+)589-trans-chlorohydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) benzene disolvate

: 82338-57-6
(+)589-trans-carbonylhydridobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) hexafluorophosphate acetone disolvate

Guidance literature:: With CO; In ethanol; CO passed into boiling soln. of Ru complex in ethanol for 10 min, excess of aq. NH4PF6 added to mixt., while CO stream maintained; mixt. cooled to -10°C, solid isolated, washed with water, dried,recrystd. from acetone by addn. of diethyl ether, dried at 100°C(0.1 mmHg);