C₂₇H₃₇NO₂Si

Base Information

• Chemical Name: C₂₇H₃₇NO₂Si
• CAS No.: 935673-58-8
• Molecular Formula: C₂₇H₃₇NO₂Si
• Molecular Weight: 435.682
• Mol file: 935673-58-8.mol

Synonyms:C₂₇H₃₇NO₂Si

Chemical Property of C₂₇H₃₇NO₂Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₃₇NO₂Si

There total 1 articles about C₂₇H₃₇NO₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C22H29BrMgOSi + piperidine-2,6-dione (1121-89-7) → C27H37NO2Si (935673-58-8)

Guidance literature:

piperidine-2,6-dione; With methylmagnesium chloride; In tetrahydrofuran; at 0 - 20 ℃;

C₂₂H₂₉BrMgOSi; In tetrahydrofuran; at 20 ℃; for 12h;

With sodium cyanoborohydride; acetic acid; In tetrahydrofuran; at 20 ℃; for 0.75h; Further stages.;

DOI:10.1021/jo062533h

Reference yield: 93.0%

C27H37NO2Si (935673-58-8) → C27H37NOSSi (935673-60-2)

Guidance literature:

With Lawessons reagent; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1021/jo062533h

Reference yield:

C27H37NO2Si (935673-58-8) → C33H43NO5Si (935673-57-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 93 percent / Lawesson's reagent / tetrahydrofuran / 1 h / 20 °C

2: 91 percent / K₂CO₃ / acetone / 6 h / 20 °C

3: 79 g / Ni(acac)2 / CHCl₃ / 6 h / Heating

With Lawessons reagent; potassium carbonate; bis(acetylacetonate)nickel(II); In tetrahydrofuran; chloroform; acetone;

DOI:10.1021/jo062533h

upstream raw materials:

piperidine-2,6-dione

Downstream raw materials:

C₂₇H₃₇NOSSi

C₂₈H₃₉NO₂Si

C₃₃H₄₃NO₅Si

C₂₈H₃₉NOSSi