trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

Base Information

Chemical Name:trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)
CAS No.:163362-39-8
Molecular Formula:C₂₁H₃₅NNiP₂
Molecular Weight:422.153
Hs Code.:

Synonyms:trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

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Chemical Property of trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

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Technology Process of trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

There total 1 articles about trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: trans-{Ni(2,4,6-C₆H₂Me₃)Br(PMe₃)2}

: 19642-99-0
potassium anilide

: 163362-39-8
trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

Guidance literature:: In tetrahydrofuran; Ar-atmosphere; addn. of excess amide to Ni-complex, cooling to -78°C for 1 h, warming to room temp., stirring for 24 h; solvent removal (reduced pressure), extn. into pentane, concn. (reducedpressure), crystn. (-10°C); elem. anal.;
DOI:10.1021/ic00125a035

Reference yield: 80.0%

: 163362-39-8
trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

: 103-71-9
phenyl isocyanate

: 170957-91-2
trans-Ni(mesityl)[N(Ph)C(O)NHC₆H₅](PMe₃)2

Guidance literature:: In pentane; Ar-atmosphere; addn. of 1 equiv. PhNCO to Ni-complex, stirring for 12 h; crystn. on cooling to -10°C; elem. anal.;
DOI:10.1021/ic00125a035

Reference yield: 76.0%

: 163362-39-8
trans-phenylamido(2,4,6-trimethylphenyl)bis(trimethylphosphine)nickel(II)

: 124-38-9,18923-20-1
carbon dioxide

: 170957-90-1
trans-Ni(mesityl)(OC(O)NHPh)(PMe₃)2

Guidance literature:: In pentane; Ar-atmosphere; bubbling CO2 through soln. of Ni-complex for 5 min (pptn.); cooling to -78°C, collection; elem. anal.;
DOI:10.1021/ic00125a035