POLY(3-DODECYLTHIOPHENE)

Base Information

• Chemical Name: POLY(3-DODECYLTHIOPHENE)
• CAS No.: 104934-53-4
• Molecular Formula: C₁₆H₂₈S
• Molecular Weight: 252.464
• Mol file: 104934-53-4.mol

Synonyms:POLY(3-DODECYLTHIOPHENE);3-DODECYLTHIOPHENE POLYMER;3-Dodecylthiophene polymer, Poly(3-dodecylthiophene-2,5-diyl), regiorandom, Poly(3-dodecylthiophene-2,5-diyl), regioregular

Chemical Property of POLY(3-DODECYLTHIOPHENE)

Chemical Property:

• PSA: 28.24000
• LogP: 5.81190

Purity/Quality:

97% ^*data from raw suppliers

Poly(3-dodecylthiophene-2,5-diyl),regioregular ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: POLY(3-DODECYLTHIOPHENE), a conducting polymer, has diverse applications in different fields. In the field of organic electronics, it serves as a key material for manufacturing organic photovoltaic cells, organic light-emitting diodes (OLEDs), and organic thin-film transistors (OTFTs). Its role is pivotal in enabling the development of flexible and lightweight electronic devices, including solar panels, displays, and sensors. Additionally, in materials science and academic research, this conducting polymer can be employed as a model material for studying the electrical and optical properties of organic semiconductors, contributing to our understanding of organic electronics. Moreover, in the field of sensors and biosensors, it can be used as a sensitive and selective material for detecting various analytes, including gases, ions, and biomolecules, leading to advancements in chemical and biological sensing technologies. Its multifaceted applications underscore its significance in electronics, materials science, and sensor technology, ultimately supporting innovations in renewable energy, display technology, and analytical chemistry.

Technology Process of POLY(3-DODECYLTHIOPHENE)

There total 7 articles about POLY(3-DODECYLTHIOPHENE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-Bromothiophene (872-31-1) + dodecylzinc(II) bromide (869589-06-0) → 3-dodecylthiophene (104934-52-3,104934-53-4)

Guidance literature:

With [1,1'-bis(diphenylphosphino)-ferrocene]palladium(II) chloride-dichlormethane complex; In N,N-dimethyl acetamide; at 80 ℃; for 12h;

Reference yield: 88.0%

3-Bromothiophene (872-31-1) + 1-dodecylbromide (143-15-7) → 3-dodecylthiophene (104934-52-3,104934-53-4)

Guidance literature:

1-dodecylbromide; With iodine; magnesium; In tetrahydrofuran; at 70 ℃; for 2h; Inert atmosphere;

3-Bromothiophene; With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In tetrahydrofuran; at 20 ℃;

Reference yield: 84.0%

3-Bromothiophene (872-31-1) + 1-Iodododecane (4292-19-7) → 3-dodecylthiophene (104934-52-3,104934-53-4)

Guidance literature:

With pyridine; manganese; Tri(p-tolyl)phosphine; trifluoroacetic acid; cobalt(II) bromide; In N,N-dimethyl acetamide; at 70 ℃; for 24h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere;

DOI:10.1002/ejoc.201500784

upstream raw materials:

3-Bromothiophene

laurylmagnesium bromide

1-dodecylbromide

5,5-dimethyl-2-(thiophen-3-yl)-1,3,2-dioxaborinane

Downstream raw materials:

2-(4-dodecylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(3-dodecylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(4-dodecylthiophen-2-yl)trimethylstannane