bis(trichlorophosphine)molybdenum tetracarbonyl

Base Information

• Chemical Name: bis(trichlorophosphine)molybdenum tetracarbonyl
• CAS No.: 16244-51-2
• Molecular Formula: C₄Cl₆MoO₄P₂
• Molecular Weight: 482.647
• Mol file: 16244-51-2.mol

Synonyms:bis(trichlorophosphine)molybdenum tetracarbonyl

Chemical Property of bis(trichlorophosphine)molybdenum tetracarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(trichlorophosphine)molybdenum tetracarbonyl

There total 1 articles about bis(trichlorophosphine)molybdenum tetracarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + phosphorus trichloride (7719-12-2,52843-90-0) → bis(trichlorophosphine)molybdenum tetracarbonyl (16244-51-2) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0)

Guidance literature:

In tetrahydrofuran; reaction in a calorimeter under argon;

Reference yield: 85.0%

(PCl3)2Mo(CO)4 (16244-51-2) → cis-PhN(P(NHPh)2)2Mo(CO)4*0.5C7H8

Guidance literature:

With triethylamine; aniline; In benzene; byproducts: Et3NHCl; N2 atmosphere, addn. soln. of aniline to soln. of Mo-compd. and Et3N (0°C); filtration, removal volatiles (vac.), recrystn. (toluene);

Reference yield: 60.0%

bis(trichlorophosphine)molybdenum tetracarbonyl (16244-51-2) → Mo(CO)4(C6H5N)(P(NHC6H5)2)2 (82991-18-2)

Guidance literature:

With triethylamine; aniline; In toluene; 0°C, N2 atm.; filtration, concn. in vac., crystn.;

DOI:10.1016/S0020-1693(00)93497-2

upstream raw materials:

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾

phosphorus trichloride

Downstream raw materials:

Mo(CO)4(C₆H₅N)(P(NHC₆H₅)2)2

Refernces