4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

Base Information

Chemical Name:4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde
CAS No.:219640-43-4
Molecular Formula:C₄₃H₆₉I₂NO
Molecular Weight:869.836
Hs Code.:

Synonyms:4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

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Chemical Property of 4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

Chemical Property:

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Technology Process of 4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

There total 7 articles about 4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3344-70-5
1,12-dibromododecane

: 219640-43-4
4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Mg, iodine, 2.) Li₂CuCl₄ / 1.) THF, reflux, 0.5 h, 2.) THF, RT, overnight

2: 60 percent / iodine, H₅IO₆, acetic acid, 30 percent sulfuric acid / CHCl₃ / 48 h / 80 °C

3: 78 percent / K₂CO₃, nBu₄Br, NaI / Heating

4: 1.) POCl₃ / 1.) a) 0 deg C, 1 h, b) RT, 1 h, 2.) 90 deg C, overnight

With dilithium tetrachlorocuprate; sulfuric acid; tetrabutylammomium bromide; iodine; potassium carbonate; magnesium; acetic acid; periodic acid; sodium iodide; trichlorophosphate; In chloroform;
DOI:10.1021/ja9825130

Reference yield:

: 106-37-6
1.4-dibromobenzene

: 219640-43-4
4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Mg, 2.) PdCl₂(dppf) / 1.) ether, reflux, 0.5 h, 2.) ether, reflux, overnight

2: 1.) Mg, iodine, 2.) Li₂CuCl₄ / 1.) THF, reflux, 0.5 h, 2.) THF, RT, overnight

3: 60 percent / iodine, H₅IO₆, acetic acid, 30 percent sulfuric acid / CHCl₃ / 48 h / 80 °C

4: 78 percent / K₂CO₃, nBu₄Br, NaI / Heating

5: 1.) POCl₃ / 1.) a) 0 deg C, 1 h, b) RT, 1 h, 2.) 90 deg C, overnight

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; dilithium tetrachlorocuprate; sulfuric acid; tetrabutylammomium bromide; iodine; potassium carbonate; magnesium; acetic acid; periodic acid; sodium iodide; trichlorophosphate; In chloroform;
DOI:10.1021/ja9825130

Reference yield:

: 112-82-3
hexadecanyl bromide

: 219640-43-4
4-{ethyl-[12-(4-hexadecyl-2,5-diiodo-phenyl)-dodecyl]-amino}-benzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Mg, 2.) PdCl₂(dppf) / 1.) ether, reflux, 0.5 h, 2.) ether, reflux, overnight

2: 1.) Mg, iodine, 2.) Li₂CuCl₄ / 1.) THF, reflux, 0.5 h, 2.) THF, RT, overnight

3: 60 percent / iodine, H₅IO₆, acetic acid, 30 percent sulfuric acid / CHCl₃ / 48 h / 80 °C

4: 78 percent / K₂CO₃, nBu₄Br, NaI / Heating

5: 1.) POCl₃ / 1.) a) 0 deg C, 1 h, b) RT, 1 h, 2.) 90 deg C, overnight

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; dilithium tetrachlorocuprate; sulfuric acid; tetrabutylammomium bromide; iodine; potassium carbonate; magnesium; acetic acid; periodic acid; sodium iodide; trichlorophosphate; In chloroform;
DOI:10.1021/ja9825130