PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water

Base Information

• Chemical Name: PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water
• CAS No.: 405883-56-9
• Molecular Formula: C₁₄H₈FeN₆*C₂₄H₂₀P*H₂O
• Molecular Weight: 673.517
• Mol file: 405883-56-9.mol

Synonyms:PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water

Chemical Property of PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water

There total 1 articles about PPh₄[iron(III)(2,2'-bipyridine)(CN)4] * water which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

K2[Fe(II)(2,2'-bipyridine)(CN)4]*3H2O + tetraphenyl phosphonium chloride (2001-45-8) → PPh4[iron(III)(2,2'-bipyridine)(CN)4] * water (405883-56-9)

Guidance literature:

With Cl₂; In water; Cl2 gas was bubbled through a warm soln. of Fe complex for 30 min with stirring, soln. of PPh4Cl was added; ppt. was filtered, recrystd. from MeCN; elem. anal.;

DOI:10.1021/ic0107882

Reference yield:

PPh4[iron(III)(2,2'-bipyridine)(CN)4] * water (405883-56-9) + [Mn(III)(N,N'-ethylenebis(salicylideneiminato)(2-))]ClO4*2H2O → [Mn(III)(N,N'-ethylenebis(salicylideneiminato)(2-))][Fe(III)(2,2'-bipyridine)(CN)4]

Guidance literature:

In methanol; acetonitrile; soln. of Mn compd. in MeOH added to soln. of Fe complex in MeCN; filtered; filtrate left to slow evapn. in dark at room temp. for 2 d; crystals washed with MeOH and H2O; dried in air; elem. anal.;

DOI:10.1016/j.molstruc.2009.01.039

upstream raw materials:

tetraphenyl phosphonium chloride