6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole

Base Information

• Chemical Name: 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole
• CAS No.: 503026-37-7
• Molecular Formula: C₁₆H₂₂O₅
• Molecular Weight: 294.348

Synonyms:6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole

Chemical Property of 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole

There total 9 articles about 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

p-methoxybenzyl chloride (824-94-2) + 5-deoxy-1,2-O-isopropylidene-β-L-arabinofuranose (33156-02-4) → 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole (503026-37-7)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃;

DOI:10.1016/j.tet.2007.12.042

Reference yield: 95.0%

p-Methoxybenzyl bromide (2746-25-0) + 5-deoxy-1,2-O-isopropylidene-β-L-arabinofuranose (33156-02-4) → 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole (503026-37-7)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 4h;

DOI:10.1016/S0040-4039(02)02284-0

Reference yield: 79.0%

6-(4-methoxybenzyloxy)-5-(4-methylphenylsulfonyloxy-methyl)-2,2-dimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole (1312551-43-1) → 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole (503026-37-7)

Guidance literature:

With sodium tetrahydroborate; In dimethyl sulfoxide; at 0 - 160 ℃; Inert atmosphere;

DOI:10.1039/c1ob00019e

upstream raw materials:

p-Methoxybenzyl bromide

5-deoxy-1,2-O-isopropylidene-β-L-arabinofuranose

1,2-O-isopropylidene-β-L-arabinofuranose

5-O-p-toluenesulfonyl-1,2-O-isopropylidene-L-arabinofuranose

Downstream raw materials:

5-deoxy-3-O-(4-methoxybenzyl)-β-L-arabinofuranose

(E)-(4R,5S)-4-(4-Methoxy-benzyloxy)-5-{(E)-(4R,5S)-4-(4-methoxy-benzyloxy)-5-[(R)-3-(2-methoxy-ethoxymethoxy)-butyryloxy]-hex-2-enoyloxy}-hex-2-enoic acid 2-(toluene-4-sulfonyl)-ethyl ester

(E)-(4R,5S)-4-(4-Methoxy-benzyloxy)-5-{(E)-(4R,5S)-4-(4-methoxy-benzyloxy)-5-[(S)-3-(2-methoxy-ethoxymethoxy)-butyryloxy]-hex-2-enoyloxy}-hex-2-enoic acid 2-(toluene-4-sulfonyl)-ethyl ester

(E)-(4R,5S)-5-[(E)-(4R,5S)-5-((R)-3-Hydroxy-butyryloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyloxy]-4-(4-methoxy-benzyloxy)-hex-2-enoic acid 2-(toluene-4-sulfonyl)-ethyl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 503026-37-7 6-(4-methoxybenzyloxy)-2,2,5-trimethyl-(3aR,5S,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole

Send

Send

Metric Ton KG G Pound L ML

Send

Send