Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

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Chemical Name:Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester
CAS No.:660403-80-5
Molecular Formula:C₅₈H₇₇NO₁₀
Molecular Weight:948.25
Hs Code.:

Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

Synonyms:Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

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Chemical Property of Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

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Technology Process of Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

There total 4 articles about Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 125164-10-5
6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

: 660403-56-5
(4S,5R)-3-((2S,3R)-3-Hydroxy-2,16-dimethyl-heptadecanoyl)-4-methyl-5-phenyl-oxazolidin-2-one

: 660403-80-5
Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

: Acetic acid (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In acetonitrile; at -30 ℃; for 2h;
DOI:10.1021/jo035079f

Reference yield:

: 3344-77-2
12-bromododecanol

: 660403-80-5
Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 98 percent / Li₂CuCl₄ / tetrahydrofuran; diethyl ether / 0 - 20 °C

2.1: 86 percent / pyridinium chlorochromate / CH₂Cl₂ / 2 h

3.1: n-Bu₂BOTf; triethylamine / CH₂Cl₂ / 0.5 h / -5 °C

3.2: 61 percent / CH₂Cl₂ / 1.25 h / -78 - 20 °C

4.1: trimethylsilyl trifluoromethanesulfonate / acetonitrile / 2 h / -30 °C

With dilithium tetrachlorocuprate; trimethylsilyl trifluoromethanesulfonate; di-n-butylboryl trifluoromethanesulfonate; triethylamine; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/jo035079f

Reference yield:

: 20194-48-3
14-methylpentadecan-1-ol

: 660403-80-5
Acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-{(R)-14-methyl-1-[(S)-1-methyl-2-((4S,5R)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-pentadecyloxy}-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 86 percent / pyridinium chlorochromate / CH₂Cl₂ / 2 h

2.1: n-Bu₂BOTf; triethylamine / CH₂Cl₂ / 0.5 h / -5 °C

2.2: 61 percent / CH₂Cl₂ / 1.25 h / -78 - 20 °C

3.1: trimethylsilyl trifluoromethanesulfonate / acetonitrile / 2 h / -30 °C

With trimethylsilyl trifluoromethanesulfonate; di-n-butylboryl trifluoromethanesulfonate; triethylamine; pyridinium chlorochromate; In dichloromethane; acetonitrile;
DOI:10.1021/jo035079f