Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Base Information

Chemical Name:Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside
CAS No.:137439-15-7
Molecular Formula:C₆₁H₅₈O₁₉
Molecular Weight:1095.12
Hs Code.:

Synonyms:Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

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Chemical Property of Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

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Technology Process of Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

There total 7 articles about Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 137439-14-6
C₆₈H₆₄O₁₉

: 137439-15-7
Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; ethyl acetate; at 40 ℃;
DOI:10.1016/0008-6215(92)80010-X

Reference yield:

: 112107-24-1
methyl 4-O-benzyl-3-O-(4-methoxybenzyl)-α-L-rhamnopyranoside

: 137439-15-7
Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: (Me₂N)2CO, molecular sieves 4 Angstroem / nitromethane / 2.5 h / -30 - -25 °C

2: 59 percent / (NH₄)2Ce(NO₃)6 / acetonitrile; H₂O / 0.33 h / 20 °C

3: 83 percent / Hg(CN)2, HgBr₂ / acetonitrile / 0.33 h / Ambient temperature

4: 91 percent / H₂ / 10percent Pd/C / ethanol; ethyl acetate / 40 °C

With ammonium cerium(IV) nitrate; 4 A molecular sieve; hydrogen; mercury(II) cyanide; tetramethylurea; mercury dibromide; palladium on activated charcoal; In nitromethane; ethanol; water; ethyl acetate; acetonitrile;
DOI:10.1016/0008-6215(92)80010-X

Reference yield:

: 25019-69-6
methyl 4-O-benzyl-α-L-rhamnopyranoside

: 137439-15-7
Methyl 2-O-(2,3,4-tri-O-benzoyl-β-L-fucopyranosyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 1)Bu₂SnO; 2)Bu₄NBr / 1)benzene, reflux, 7 h; 2)benzene, 50 - 60 deg C, 1.5 h

2: (Me₂N)2CO, molecular sieves 4 Angstroem / nitromethane / 2.5 h / -30 - -25 °C

3: 59 percent / (NH₄)2Ce(NO₃)6 / acetonitrile; H₂O / 0.33 h / 20 °C

4: 83 percent / Hg(CN)2, HgBr₂ / acetonitrile / 0.33 h / Ambient temperature

5: 91 percent / H₂ / 10percent Pd/C / ethanol; ethyl acetate / 40 °C

With ammonium cerium(IV) nitrate; 4 A molecular sieve; tetrabutylammomium bromide; hydrogen; mercury(II) cyanide; di(n-butyl)tin oxide; tetramethylurea; mercury dibromide; palladium on activated charcoal; In nitromethane; ethanol; water; ethyl acetate; acetonitrile;
DOI:10.1016/0008-6215(92)80010-X