cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Base Information

Chemical Name:cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate
CAS No.:474457-45-9
Molecular Formula:C₂₂H₂₀Br₂N₂O₃
Molecular Weight:520.22
Hs Code.:

Synonyms:cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

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Chemical Property of cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

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Technology Process of cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

There total 5 articles about cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 474457-44-8
cyano[3-(4-nitrophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

: 474457-45-9
cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: With tin(ll) chloride; In ethanol; at 70 - 75 ℃; for 0.583333h;
DOI:10.1021/jf0207629

Reference yield:

: 53179-78-5,59952-39-5,61914-48-5,63538-10-3,63597-73-9,63949-77-9,72691-16-8,72691-18-0,74560-76-2
2,2-dimethyl-3R-(2',2'-dibromovinyl)-cyclopropane-1R-carboxylic acid

: 474457-45-9
cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: SOCl₂; DMF / CHCl₃ / 1 h / 60 - 65 °C

2: 95 percent / pyridine / CHCl₃ / 0.5 h / 20 °C

3: 64 percent / SnCl₂ / ethanol / 0.58 h / 70 - 75 °C

With pyridine; thionyl chloride; N,N-dimethyl-formamide; tin(ll) chloride; In ethanol; chloroform;
DOI:10.1021/jf0207629

Reference yield:

: 17076-72-1
3-(4-nitrophenoxy)benzaldehyde

: 474457-45-9
cyano[3-(4-aminophenoxy)phenyl]methyl 1R-cis-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: ZnI₂ / CHCl₃ / 2.5 h / 20 °C

2: 95 percent / pyridine / CHCl₃ / 0.5 h / 20 °C

3: 64 percent / SnCl₂ / ethanol / 0.58 h / 70 - 75 °C

With pyridine; tin(ll) chloride; zinc(II) iodide; In ethanol; chloroform;
DOI:10.1021/jf0207629