1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀

Base Information

• Chemical Name: 1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀
• CAS No.: 1304037-83-9
• Molecular Formula: C₁₆H₁₈B₁₀F₆
• Molecular Weight: 432.419
• Mol file: 1304037-83-9.mol

Synonyms:1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀

Chemical Property of 1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀

There total 3 articles about 1,2-(4'-CF₃C₆H₄)2-1,2-closo-C₂B₁₀H₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

decaborane + 1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → 1,2-(4'-CF3C6H4)2-1,2-closo-C2B10H10 (1304037-83-9)

Guidance literature:

With N,N-dimethylaniline; In toluene; under N2; B10H14 dissolved in degassed toluene; N,N-dimethylaniline added; stirred at 50°C for 1 h; CF3C6H4C2C6H4CF3 added; heated to reflux for 18 h; concd. under reduced pressure at 50°C; purified by column chromy.(silica, petroleum ether); elem. anal.;

DOI:10.1039/c0dt01798a

Reference yield: 56.0%

1,2-dicarba-closo-dodecaborane(12) (16872-09-6) + 4-Iodobenzotrifluoride (455-13-0) → 1,2-(4'-CF3C6H4)2-1,2-closo-C2B10H10 (1304037-83-9)

Guidance literature:

1,2-dicarba-closo-dodecaborane⁽¹²⁾; With isopropylmagnesium chloride; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;

4-Iodobenzotrifluoride; With nickel dichloride; In toluene; at 100 ℃; for 8h; Inert atmosphere;

DOI:10.1002/anie.201502502

Reference yield:

1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → 1,2-(4'-CF3C6H4)2-1,2-closo-C2B10H10 (1304037-83-9)

Guidance literature:

With silver nitrate; In toluene; at 100 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201904940

upstream raw materials:

1,2-bis(4-(trifluoromethyl)phenyl)ethyne

1,2-dicarba-closo-dodecaborane⁽¹²⁾

4-Iodobenzotrifluoride