(C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅)

Base Information

• Chemical Name: (C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅)
• CAS No.: 81423-53-2
• Molecular Formula: C₂₈H₃₆PRh
• Molecular Weight: 506.473
• Mol file: 81423-53-2.mol

Synonyms:(C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅)

Chemical Property of (C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅)

There total 3 articles about (C₅H₅)Rh(P(CH(CH₃)2)3)(C₆H₅CCC₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

trans-[RhCl(PhCCPh)(PiPr3)2] (131564-13-1,85944-35-0) + sodium cyclopentadienide → (C5H5)Rh(P(CH(CH3)2)3)(C6H5CCC6H5) (81423-53-2) + tris(1-methylethyl)phosphine (6476-36-4)

Guidance literature:

In tetrahydrofuran; under Ar, soln. of Rh complex in THF mixed with NaC5H5, stirred at room temp. for 3 h; evapd., residue extracted with hexane, evapd. in vac., dried in vac. for 6 h, dissolved in hexane, chromd., evapd., recrystd. from THF/pentane,elem. anal.;

DOI:10.1016/S0022-328X(00)98566-8

Reference yield: 84.0%

trans-[RhCl(PhCCPh)(PiPr3)2] (131564-13-1,85944-35-0) → (C5H5)Rh(P(CH(CH3)2)3)(C6H5CCC6H5) (81423-53-2)

Guidance literature:

With NaC₅H₅; In tetrahydrofuran; byproducts: NaCl, P(i-Pr)3; (Ar), mixture stirred at room temp. for 2 h; solvent removed, extracted with hexane, volume reduced in vac., dried in vac., dissolved in hexane, chromy.( Al2O3), solvent removed, recrystd.from THF/pentane at -78°C; elem. anal.;

DOI:10.1016/0022-328X(86)80543-5

Reference yield:

(C5H5)Rh(CH3)(C(C6H5)CH(C6H5))(P((CH3)2CH)3) → (C5H5)Rh(P(CH(CH3)2)3)(C6H5CCC6H5) (81423-53-2)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: CH4; (Ar), heated at 120°C for 30 min; cooled; IR, NMR;

DOI:10.1016/0022-328X(86)80543-5

upstream raw materials:

trans-[RhCl(PhCCPh)(PiPr₃)2]

Downstream raw materials:

Rh(C₅H₅)(PC(C(CH₃)3)C(C₆H₅)C(C₆H₅))

Rh(C₅H₅)(PC(N(CH(CH₃)2)(Si(CH₃)3))C(C₆H₅)C(C₆H₅))

Refernces

• 1、 Werner, H.,Wolf, J.,Schubert, U.,Ackermann, K.. "BASISCHE METALLE. XLIV. DARSTELLUNG UND PROTONIERUNG DER KOMPLEXE C5H5Rh(C2R2)PPri3: ZUR UMWANDLUNG EINER RHODIUM-TOLAN- IN EINE ISOMERE RHODAINDEN-VERBINDUNG". . p. C63 - C70. Retrieved 2007/10/02.