(E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime

Base Information

• Chemical Name: (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime
• CAS No.: 1378939-17-3
• Molecular Formula: C₂₂H₁₈BrNO
• Molecular Weight: 392.295
• Mol file: 1378939-17-3.mol

Synonyms:(E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime

Chemical Property of (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime

There total 1 articles about (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

syn-benzaldehyde oxime (932-90-1,622-31-1,140461-24-1,140461-25-2,622-32-2) + rac-(E)-3-(2-bromophenyl)-1-phenylallyl acetate (1378939-16-2) → (E)-benzaldehyde O-((E)-1-(2-bromophenyl)-3-phenylallyl)oxime (1378939-18-4) + (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime (1378939-17-3)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); (S)-4-(tert-butyl)-2-(2-(diphenylphosphino)-1-(methoxymethyl)-1H-indol-3-yl)-4,5-dihydro-oxazole; caesium carbonate; In tetrahydrofuran; at 0 - 20 ℃; for 18h;

DOI:10.1055/s-0031-1290607

Reference yield:

(E)-benzaldehyde O-((E)-1-(2-bromophenyl)-3-phenylallyl)oxime (1378939-18-4) + (E)-benzaldehyde O-((E)-3-(2-bromophenyl)-1-phenylallyl)oxime (1378939-17-3) → (E)-3-(2-bromophenyl)-1-phenylprop-2-en-1-ol + (E)-1-(2-bromophenyl)-3-phenylprop-2-en-1-ol + (E)-3-(2-bromophenyl)-1-phenylprop-2-en-1-ol + (E)-1-(2-bromophenyl)-3-phenylprop-2-en-1-ol

Guidance literature:

With acetic acid; zinc; In water; at 20 ℃; for 2h; optical yield given as %ee; enantioselective reaction;

DOI:10.1055/s-0031-1290607

upstream raw materials:

syn-benzaldehyde oxime

rac-(E)-3-(2-bromophenyl)-1-phenylallyl acetate