{Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)}

Base Information

• Chemical Name: {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)}
• CAS No.: 83970-82-5
• Molecular Formula: C₁₈H₂₀MnO₆
• Molecular Weight: 387.291
• Mol file: 83970-82-5.mol

Synonyms:{Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)}

Chemical Property of {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)}

There total 2 articles about {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Mn(CO)5(O-o-3,5-di-tert-butyl-1,2-benzosemiquinone) → dimanganese decacarbonyl (10170-69-1) + {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)} (83970-82-5)

Guidance literature:

In not given; warming soln. from 180 to 195 K; not isolated, IR, EPR;

DOI:10.1016/0022-328X(91)86228-I

Reference yield:

2Mn*9CO + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9) → dimanganese decacarbonyl (10170-69-1) + {Mn(CO)4(3,5-di-tert-butyl-1,2-semiquinone radical anion)} (83970-82-5) + Mn2(CO)9(3,5-di-tert-butyl-1,2-benzoquinone)

Guidance literature:

In solid matrix; 2-chlorobutane glass contg. Mn2(CO)9 and excess of quinone warmed to 220 K; not isolated, IR;

DOI:10.1016/0022-328X(91)86228-I

upstream raw materials:

3,5-di-tert-butyl-o-benzoquinone