tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

Base Information

Chemical Name:tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane
CAS No.:1054608-49-9
Molecular Formula:C₃₈H₆₉IO₇Si₂
Molecular Weight:821.037
Hs Code.:

tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

Synonyms:tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

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Chemical Property of tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

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Technology Process of tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

There total 1 articles about tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 1054608-48-8
tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl-6-((S)-3-methylhex-4-ynyl)tetrahydro-2H-pyran-4-yloxy)dimethylsilane

: 1054608-49-9
tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

Guidance literature:: tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyl-6-((S)-3-methylhex-4-ynyl)tetrahydro-2H-pyran-4-yloxy)dimethylsilane; With tri-n-butyl-tin hydride; palladium diacetate; tricyclohexylphosphine; In tetrahydrofuran; hexane; Inert atmosphere;

With N-iodo-succinimide; In chloroacetonitrile; acetonitrile; at 20 ℃; for 1h; Inert atmosphere; Darkness;
DOI:10.1021/ol801499s

Reference yield: 92.0%

: 1054608-36-4
tert-butyl((2S,4S)-5-iodo-2,4-dimethylpentyloxy)dimethylsilane

: 1054608-49-9
tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

: 1054608-51-3
tert-butyl((2R,3S,4S,5S,6R)-2-((3S,7S,9S,E)-10-(tert-butyldimethylsilyloxy)-3,5,7,9-tetramethyldec-4-enyl)-6-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane

Guidance literature:: tert-butyl((2S,4S)-5-iodo-2,4-dimethylpentyloxy)dimethylsilane; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.166667h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; pentane; at -78 - 0 ℃; Inert atmosphere;

tert-butyl((2R,3S,4S,5S,6R)-2-(2-(tert-butyldimethylsilyloxy)-3,5-dimethoxy-6-((methoxymethoxy)methyl)-4-methylphenyl)-6-((S,E)-5-iodo-3-methylhex-4-enyl)-3,5-dimethyltetrahydro-2H-pyran-4-yloxy)dimethylsilane; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; pentane; at 0 - 20 ℃; Inert atmosphere; Darkness;
DOI:10.1021/ol801499s