6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

Base Information

Chemical Name:6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one
CAS No.:1044779-89-6
Molecular Formula:C₂₁H₂₇BrN₂O₇S
Molecular Weight:531.425
Hs Code.:

Synonyms:6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

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Chemical Property of 6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

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Technology Process of 6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

There total 1 articles about 6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 892861-49-3
4-bromo-2-(2-nitroethyl)-N-p-tosylpyrrole

: 127256-03-5
1,1,-dimethoxy-4-methyl-3-penten-2-one

: 1044779-89-6
6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

Guidance literature:: With cesium fluoride; In acetonitrile; at 20 ℃; for 24h;
DOI:10.1039/b717803d

Reference yield: 80.0%

: 1044779-89-6
6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

: 38330-80-2
monomethyl monopotassium malonate

: 6-[4-(3-methoxy-3-oxopropanoyl)-N-tosylpyrrol-2-yl]-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

Guidance literature:: With 1H-imidazole; dicobalt octacarbonyl; palladium diacetate; triethylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; magnesium chloride; In tetrahydrofuran; at 65 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.joc.6b02878

Reference yield: 56.0%

: 1044779-89-6
6-(4-bromo-N-tosylpyrrol-2-yl)-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

: 6148-64-7
ethyl potassium malonate

: 6-[4-(3-ethoxy-3-oxopropanoyl)-N-tosylpyrrol-2-yl]-1,1-dimethoxy-4,4-dimethyl-5-nitrohexan-2-one

Guidance literature:: With 1H-imidazole; dicobalt octacarbonyl; palladium diacetate; triethylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; magnesium chloride; In tetrahydrofuran; at 65 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.joc.6b02878