ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

Base Information

Chemical Name:ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate
CAS No.:80360-92-5
Molecular Formula:C₁₇H₂₀O₂S
Molecular Weight:288.411
Hs Code.:

Synonyms:ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

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Chemical Property of ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

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Technology Process of ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

There total 6 articles about ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80361-27-9
(Z)-2-<(phenylthio)methyl>but-2-en-1-ol

: 80360-92-5
ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / oxalyl chloride, Me₂SO / CH₂Cl₂ / 0.25 h / -78 °C

3: 1.) NaH / 1.) THF, below 30 deg C, 1 h, 2.) 60 deg C, 15 min

With oxalyl dichloride; sodium hydride; dimethyl sulfoxide; In dichloromethane;
DOI:10.1021/jo00347a034

Reference yield:

: 80360-82-3
(Z)-ethyl 2-<(phenylthio)methyl>-2-butenoate

: 80360-92-5
ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

Guidance literature:: Multi-step reaction with 4 steps

1: DIBAL / CH₂Cl₂; hexane / 0.5 h / -78 °C

2: 77 percent / oxalyl chloride, Me₂SO / CH₂Cl₂ / 0.25 h / -78 °C

4: 1.) NaH / 1.) THF, below 30 deg C, 1 h, 2.) 60 deg C, 15 min

With oxalyl dichloride; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; In hexane; dichloromethane;
DOI:10.1021/jo00347a034

Reference yield:

: 80360-81-2
3-Methanesulfonyloxy-2-phenylsulfanylmethyl-butyric acid ethyl ester

: 80360-92-5
ethyl 6-<(phenylthio)methyl>-2,4,6-octatrienoate

Guidance literature:: Multi-step reaction with 5 steps

1: DBU / tetrahydrofuran / 2 h / 45 °C

2: DIBAL / CH₂Cl₂; hexane / 0.5 h / -78 °C

3: 77 percent / oxalyl chloride, Me₂SO / CH₂Cl₂ / 0.25 h / -78 °C

5: 1.) NaH / 1.) THF, below 30 deg C, 1 h, 2.) 60 deg C, 15 min

With oxalyl dichloride; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo00347a034