methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

Base Information

• Chemical Name: methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside
• CAS No.: 98383-29-0
• Molecular Formula: C₁₆H₁₉N₃O₆
• Molecular Weight: 349.343
• Mol file: 98383-29-0.mol

Synonyms:methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

Chemical Property of methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside

There total 1 articles about methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methyl 3-O-acetyl-4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-arabino-hexopyranoside (98383-28-9) → methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside (98383-29-0)

Guidance literature:

With sodium azide; In N,N-dimethyl-formamide; at 80 ℃; for 8h;

DOI:10.1021/jm00121a005

Reference yield:

methyl 3-O-acetyl-6-azido-4-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside (98383-29-0) → C10H18ClN3O6 (98383-32-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 98 percent / 1 M sodium methoxide / methanol / 18 h / Ambient temperature

2: 98 percent / H₂, Et₃N / 10percent Pd/C / ethanol

3: dimethylformamide / 5 h / 0 °C

4: sodium nitrite / formic acid / 0.5 h

With hydrogen; sodium methylate; triethylamine; sodium nitrite; palladium on activated charcoal; In methanol; formic acid; ethanol; N,N-dimethyl-formamide;

DOI:10.1021/jm00121a005

upstream raw materials:

methyl 3-O-acetyl-4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-arabino-hexopyranoside

Downstream raw materials:

C₁₀H₁₈ClN₃O₆