1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene

Base Information

• Chemical Name: 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene
• CAS No.: 909901-91-3
• Molecular Formula: C₃₃H₂₅NO₄
• Molecular Weight: 499.566
• Mol file: 909901-91-3.mol

Synonyms:1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene

Chemical Property of 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene

There total 3 articles about 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

2-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)phenyl]pyridine (453530-49-9) + dimethyl 5’-bromo-(1,1’:3’,1’’-terphenyl)-4,4’’-dicarboxylate → 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene (909901-91-3)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; toluene; for 24h; Heating;

DOI:10.1246/cl.2006.720

Reference yield:

1,3,5-trisbromobenzene (626-39-1) → 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene (909901-91-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / aq. Na₂CO₃ / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / ethanol; toluene / 24 h / Heating

2: 36 percent / aq. Na₂CO₃ / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / ethanol; toluene / 24 h / Heating

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; toluene;

DOI:10.1246/cl.2006.720

Reference yield:

methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate (171364-80-0) → 1-(3'-(2''-pyridyl)phenyl)-3,5-di(4'-methyloxycarbonylphenyl)bwnzene (909901-91-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / aq. Na₂CO₃ / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / ethanol; toluene / 24 h / Heating

2: 36 percent / aq. Na₂CO₃ / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / ethanol; toluene / 24 h / Heating

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; toluene;

DOI:10.1246/cl.2006.720

upstream raw materials:

2-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)phenyl]pyridine

1,3,5-trisbromobenzene

methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Downstream raw materials:

[(3,5'-di(4-methylcarboxylphenyl)-3-(2-pyridyl)biphenyl-4-yl)3 iridium(III)]