1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Base Information

Chemical Name:1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol
CAS No.:216960-10-0
Molecular Formula:C₃₁H₄₆O₄Si
Molecular Weight:510.789
Hs Code.:

Synonyms:1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Suppliers and Price of 1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

There total 3 articles about 1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 216960-08-6
1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-L-xylitol

: 216960-10-0
1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; for 1.5h;
DOI:10.1021/jo9813336

Reference yield:

: (3S,4R)-2-allyl-3,4-bis(benzyloxy)tetrahydrofuran-2-carboxylic acid

: 216960-10-0
1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Guidance literature:: Multi-step reaction with 3 steps

1: 2.57 g / diethyl ether

2: 84 percent / LiAlH₄ / diethyl ether / 1.) 0 deg C, 10 min, 2.) 0 deg C -> room temperature, overnight

3: 98 percent / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; In diethyl ether; dichloromethane;
DOI:10.1021/jo9813336

Reference yield:

: (3S,4R)-2-Allyl-3,4-bis-benzyloxy-tetrahydro-furan-2-carboxylic acid methyl ester

: 216960-10-0
1,4-anhydro-2,3-di-O-benzyl-4-C-(prop-2-enyl)-5-O-triisopropylsilyl-L-xylitol

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / LiAlH₄ / diethyl ether / 1.) 0 deg C, 10 min, 2.) 0 deg C -> room temperature, overnight

2: 98 percent / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; In diethyl ether; dichloromethane;
DOI:10.1021/jo9813336