C₅₄H₁₀₄O₁₂SSi₄

Base Information

Chemical Name:C₅₄H₁₀₄O₁₂SSi₄
CAS No.:129986-39-6
Molecular Formula:C₅₄H₁₀₄O₁₂SSi₄
Molecular Weight:1089.82
Hs Code.:

C<sub>54</sub>H<sub>104</sub>O<sub>12</sub>SSi<sub>4</sub>

Synonyms:C₅₄H₁₀₄O₁₂SSi₄

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅₄H₁₀₄O₁₂SSi₄

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Technology Process of C₅₄H₁₀₄O₁₂SSi₄

There total 19 articles about C₅₄H₁₀₄O₁₂SSi₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 125846-32-4
3,5-O--4,9,10,11,12-pentadeoxy-6-O-<2,6-dideoxy-3-O-methyl-4-O-(triethylsilyl)-β-D-ribo-hexopyranosyl>-4-methyl-2,8-di-C-methyl-12-(phenylsulfonyl)-7,8-bis-O-(triethylsilyl)-D-xylo-L-gulo-dodecitol

: 129986-39-6
C₅₄H₁₀₄O₁₂SSi₄

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 0.5h;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-21-6
<2R,3S,4S>-2,4-O--3-methyl-5-methylene-1,2,4-hexanetriol

: 129986-39-6
C₅₄H₁₀₄O₁₂SSi₄

Guidance literature:: Multi-step reaction with 11 steps

1: 97 percent / oxalyl chloride, DMSO / CH₂Cl₂ / 0.25 h / -78 °C

3: 1.) Me₃Al / 1.) THF, toluene, RT, 15 min, 2.) 0 deg C, 2.25 h

4: Dess-Martin periodinane, pyridine / CH₂Cl₂ / 0.83 h / Ambient temperature

5: 70 percent / trityl perchlorate / toluene / 1.42 h / -8 - -5 °C

6: 95 percent / LiBr / tetrahydrofuran / 0.67 h / -78 °C

7: 86 percent / H₂O, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / CH₂Cl₂ / 2.5 h / Ambient temperature

8: 1.) magnesium / 1.) THF, 40 deg C, 1 h, 2.) a) -40 deg C, 20 min, b) -25 deg C, 14.5 h

9: 1.) n-BuLi / 1.) THF, hexane, from -50 to -40 deg C, 3 min, 2.) -10 deg C, 1.6 h

10: 96 percent / N-methylmorpholine N-oxide monohydrate, aq. OsO₄ / tetrahydrofuran / 22 h

11: 87 percent / oxalyl chloride, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

With pyridine; osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; water; trimethylaluminum; triphenylmethyl perchlorate; Dess-Martin periodane; magnesium; dimethyl sulfoxide; 4-methylmorpholine N-oxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium bromide; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ja00175a038

Reference yield:

: 129986-33-0
2,6-dideoxy-3-O-methyl-4-O-(triethylsilyl)-β-D-ribo-hexopyranose acetate

: 129986-39-6
C₅₄H₁₀₄O₁₂SSi₄

Guidance literature:: Multi-step reaction with 7 steps

1: 70 percent / trityl perchlorate / toluene / 1.42 h / -8 - -5 °C

2: 95 percent / LiBr / tetrahydrofuran / 0.67 h / -78 °C

3: 86 percent / H₂O, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / CH₂Cl₂ / 2.5 h / Ambient temperature

4: 1.) magnesium / 1.) THF, 40 deg C, 1 h, 2.) a) -40 deg C, 20 min, b) -25 deg C, 14.5 h

5: 1.) n-BuLi / 1.) THF, hexane, from -50 to -40 deg C, 3 min, 2.) -10 deg C, 1.6 h

6: 96 percent / N-methylmorpholine N-oxide monohydrate, aq. OsO₄ / tetrahydrofuran / 22 h

7: 87 percent / oxalyl chloride, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

With osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; water; triphenylmethyl perchlorate; magnesium; dimethyl sulfoxide; 4-methylmorpholine N-oxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium bromide; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ja00175a038