(-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone

Base Information

• Chemical Name: (-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone
• CAS No.: 77255-27-7
• Molecular Formula: C₁₈H₁₄O₅
• Molecular Weight: 310.306

Synonyms:(-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone

Chemical Property of (-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone

Chemical Property:

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Technology Process of (-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone

There total 4 articles about (-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(+)-2,3-dihydro-2,3-epoxy-2,2'-methoxycarbonylphenyl-1,4-naphtoquinone (77199-03-2) → (-)-2,3-epoxy-trans-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone (77255-27-7) + (-)-2,3-epoxy-cis-4-hydroxy-trans-2,2'-methoxycarbonylphenyl-α-tetralone (77199-04-3)

Guidance literature:

With sodium tetrahydroborate; In methanol; at -50 ℃; for 1h;

DOI:10.1248/cpb.29.1321

Reference yield: 75.0%

2,3-dihydro-2,3-epoxy-2,2'-methoxycarbonylphenyl-1,4-naphthoquinone (77199-03-2,80300-98-7) → 2,3-epoxy-cis-4-hydroxy-trans-2-2'-methoxycarbonylphenyl-α-tetralone (77199-04-3,77255-27-7,80300-99-8,80301-00-4) + 2,3-epoxy-trans-4-hydroxy-trans-2-2'-methoxycarbonylphenyl-α-tetralone (77199-04-3,77255-27-7,80300-99-8,80301-00-4)

Guidance literature:

With lithium tri-t-butoxyaluminum hydride; In tetrahydrofuran; at -30 ℃; for 16h;

Reference yield: 75.0%

2,3-dihydro-2,3-epoxy-2,2'-methoxycarbonylphenyl-1,4-naphthoquinone (77199-03-2,80300-98-7) → 2,3-epoxy-cis-4-hydroxy-trans-2-2'-methoxycarbonylphenyl-α-tetralone (77199-04-3,77255-27-7,80300-99-8,80301-00-4) + 2,3-epoxy-trans-4-hydroxy-trans-2-2'-methoxycarbonylphenyl-α-tetralone (77199-04-3,77255-27-7,80300-99-8,80301-00-4)

Guidance literature:

With lithium tri-t-butoxyaluminum hydride; In tetrahydrofuran; at -30 ℃; for 16h;

upstream raw materials:

2,3-dihydro-2,3-epoxy-2,2'-methoxycarbonylphenyl-1,4-naphthoquinone

(+)-2,3-dihydro-2,3-epoxy-2,2'-methoxycarbonylphenyl-1,4-naphtoquinone

2,2'-methoxycarbonylphenyl-1,4-naphthoquinone

Downstream raw materials:

1,cis-4-dihydroxy-cis-2,3-epoxy-trans-2-2'-methoxycarbonylphenyl-1,2,3,4-tetrahydronaphthalene

1,cis-4-dihydroxy-cis-2,3-epoxy-trans-2-2'-methylcarbamoylphenyl-1,2,3,4-tetrahydronaphthalene

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