(1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane

Base Information

• Chemical Name: (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane
• CAS No.: 108794-46-3
• Molecular Formula: C₁₃H₁₈O₇
• Molecular Weight: 286.282
• Mol file: 108794-46-3.mol

Synonyms:(1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane

Chemical Property of (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane

There total 1 articles about (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic anhydride (108-24-7) + Acetic acid (1aR,3S,3aR,6aR,6bR)-5,5-dimethyl-hexahydro-1,4,6-trioxa-cyclopropa[e]inden-3-ylmethyl ester → DL-(1/2,3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol (10226-79-6,16656-57-8,16802-99-6,52079-86-4,60594-30-1,60594-31-2,64625-67-8,74560-70-6,74561-02-7,74561-06-1,74561-11-8,77209-45-1,90694-06-7,90695-22-0,94943-06-3,94943-07-4,97372-12-8,97372-20-8,97372-27-5,97372-29-7,102629-12-9,105017-73-0,105017-80-9,105368-83-0,108813-47-4,108813-49-6,108866-23-5,115184-61-7,115184-64-0) + (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane (108794-46-3) + DL-(1,3,4,5/2)-1,2,3,4-tetra-acetoxy-5-acetoxymethylcyclohexane (10226-79-6,16656-57-8,16802-99-6,52079-86-4,60594-30-1,60594-31-2,64625-67-8,74560-70-6,74561-02-7,74561-06-1,74561-11-8,77209-45-1,90694-06-7,90695-22-0,94943-06-3,94943-07-4,97372-12-8,97372-20-8,97372-27-5,97372-29-7,102629-12-9,105017-73-0,105017-80-9,105368-83-0,108813-47-4,108813-49-6,108866-23-5,115184-61-7,115184-64-0)

Guidance literature:

Acetic acid (1aR,3S,3aR,6aR,6bR)-5,5-dimethyl-hexahydro-1,4,6-trioxa-cyclopropa[e]inden-3-ylmethyl ester; With perchloric acid; water; for 30h;

acetic anhydride; With pyridine; Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)00408-1

Reference yield: 66.0%

acetic anhydride (108-24-7) + (1RS,2SR,3SR,4SR,5RS)-2,3,4-triacetoxy-6-oxabicyclo<3.2.1>octane (108794-46-3) → DL-(1,3,4,5/2)-1,2,3,4-tetra-acetoxy-5-acetoxymethylcyclohexane (10226-79-6,16656-57-8,16802-99-6,52079-86-4,60594-30-1,60594-31-2,64625-67-8,74560-70-6,74561-02-7,74561-06-1,74561-11-8,77209-45-1,90694-06-7,90695-22-0,94943-06-3,94943-07-4,97372-12-8,97372-20-8,97372-27-5,97372-29-7,102629-12-9,105017-73-0,105017-80-9,105368-83-0,108813-47-4,108813-49-6,108866-23-5,115184-61-7,115184-64-0)

Guidance literature:

With sulfuric acid; acetic acid; at 50 ℃; for 48h;

DOI:10.1016/S0008-6215(00)90192-7

upstream raw materials:

acetic anhydride

Downstream raw materials:

DL-(1,3,4,5/2)-1,2,3,4-tetra-acetoxy-5-acetoxymethylcyclohexane