(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

Base Information

Chemical Name:(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol
CAS No.:150807-03-7
Molecular Formula:C₂₇H₃₀O₃Si
Molecular Weight:430.619
Hs Code.:

Synonyms:(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

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Chemical Property of (2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

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Technology Process of (2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

There total 3 articles about (2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 6153-05-5,105-29-3
(Z)-3-methylpent-2-en-4-ynol

: 150852-27-0
5-bromo-1-tert-butyldiphenylsilyloxy-2,3-epoxypent-4-yne

: 150807-03-7
(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

Guidance literature:: With hydroxylamine hydrochloride; ethylamine; copper(l) chloride; In methanol; water; at 0 ℃; for 0.166667h;
DOI:10.1016/S0040-4020(01)82372-3

Reference yield:

: 144629-83-4
Butyric acid (2R,3S)-3-(2,2-dibromo-vinyl)-oxiranylmethyl ester

: 150807-03-7
(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / N sodio hexamethyldisilazane amide / tetrahydrofuran / -100 °C

3: 84 percent / CuCl, NH₄OH, EtNH₂ / methanol

With ammonium hydroxide; sodium hexamethyldisilazane; ethylamine; copper(l) chloride; In tetrahydrofuran; methanol;

Reference yield:

: 144540-67-0
Butyric acid (2R,3S)-3-bromoethynyl-oxiranylmethyl ester

: 150807-03-7
(2Z,8S,9R)-10-(tert-butyldiphenylsilyloxy)-8,9-epoxy-3-methyl-4,6-decadiyn-2-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

2: 84 percent / CuCl, NH₄OH, EtNH₂ / methanol

With ammonium hydroxide; ethylamine; copper(l) chloride; In methanol;