(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

Base Information

Chemical Name:(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol
CAS No.:781642-20-4
Molecular Formula:C₆₀H₇₆O₄Si₃
Molecular Weight:945.518
Hs Code.:

Synonyms:(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

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Chemical Property of (E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

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Technology Process of (E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

There total 5 articles about (E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 781642-19-1
C₅₈H₇₂O₃Si₃

: 781642-20-4
(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

Guidance literature:: In diethyl ether; at -78 ℃;
DOI:10.1021/ol048862i

Reference yield:

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 781642-20-4
(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

Guidance literature:: Multi-step reaction with 5 steps

1: diethyl ether / -78 °C

2: 87 percent / Cl₂Ru(C₃H₅N₂(Mes)2)(C₁₀H₁₂O) / CH₂Cl₂ / 25 °C

3: 84 percent / diethyl ether / -78 °C

4: 77 percent / imidazole / CH₂Cl₂ / 25 °C

5: diethyl ether / -78 °C

With 1H-imidazole; Cl₂Ru(C₃H₅N₂(Mes)2)(C₁₀H₁₂O); In diethyl ether; dichloromethane;
DOI:10.1021/ol048862i

Reference yield:

: 112897-09-3
(3R)-1-(tert-butyldiphenylsilyloxy)hex-5-en-3-ol

: 781642-20-4
(E)-(4S,6S,10R)-6,10,12-Tris-(tert-butyl-diphenyl-silanyloxy)-dodeca-1,7-dien-4-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 87 percent / Cl₂Ru(C₃H₅N₂(Mes)2)(C₁₀H₁₂O) / CH₂Cl₂ / 25 °C

2: 84 percent / diethyl ether / -78 °C

3: 77 percent / imidazole / CH₂Cl₂ / 25 °C

4: diethyl ether / -78 °C

With 1H-imidazole; Cl₂Ru(C₃H₅N₂(Mes)2)(C₁₀H₁₂O); In diethyl ether; dichloromethane;
DOI:10.1021/ol048862i