(R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate

Base Information

Chemical Name:(R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate
CAS No.:1189170-96-4
Molecular Formula:C₂₃H₃₀O₆Si
Molecular Weight:430.573
Hs Code.:

Synonyms:(R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate

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Technology Process of (R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate

There total 1 articles about (R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1189170-86-2
4-((2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl)phenyl pivalate

: 1066-54-2
trimethylsilylacetylene

: 1189170-96-4
(R)-4-(1-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-3-(trimethylsilyl)prop-2-ynyl)phenyl pivalate

Guidance literature:: With (S)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(bis(3,5-dimethylphanyl))phosphine; [Rh(OH)(cod)]2; In 1,2-dimethoxyethane; at 20 ℃; for 66h; optical yield given as %ee; enantioselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1021/ja905336p