ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate

Base Information

• Chemical Name: ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate
• CAS No.: 77772-29-3
• Molecular Formula: C₁₅H₂₈O₃Si
• Molecular Weight: 284.471
• Mol file: 77772-29-3.mol

Synonyms:ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate

Chemical Property of ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate

Chemical Property:

Purity/Quality:

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Technology Process of ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate

There total 1 articles about ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

4-(tert-Butyl-dimethyl-silanyloxy)-7-iodo-hept-2-ynoic acid ethyl ester (190258-58-3) → ethyl (Z)-(2-tert-butyldimethylsilyloxycyclopentylidene)acetate (77772-29-3) + (E)-1-tert-butyldimethylsilyloxy-2-phenylmethylenecyclopentane (125536-52-9)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In diethyl ether; at 80 ℃;

DOI:10.1016/S0040-4020(97)00257-3

upstream raw materials:

4-(tert-Butyl-dimethyl-silanyloxy)-7-iodo-hept-2-ynoic acid ethyl ester