Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2)

Base Information

• Chemical Name: Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2)
• CAS No.: 425603-90-3
• Molecular Formula: C₇₃H₇₈N₈O₁₄Zn
• Molecular Weight: 1356.86
• Mol file: 425603-90-3.mol

Synonyms:Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2)

Chemical Property of Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2)

There total 1 articles about Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₂CH₃(O(CH₂)6C₃H₃N₂)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-(3,5-bis[[6-(1H-imidazole-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)](2-)-N(21),N(22),N(23),N(24)]zinc(II) (425603-91-4) → Zn(HCO2CH2CH2CH2O)4C6H3C6H3C20H9N4(C6H2CH3(O(CH2)6C3H3N2)2) (425603-90-3)

Guidance literature:

With NaOH; In 1,4-dioxane; Zn-complex was dissolved in dioxane and NaOH was added, stirred in the dark at room temp. for 3 d; extd. with CHCl3, aq. phase was acidified with HCl, satd. with NaCl, filtered, washed with H2O, acetone, Et2O, dried under vac. in the dark for 2 h;

DOI:10.1002/1522-2675(200202)85:2<571::AID-HLCA571>3.0.CO;2-Y

Reference yield: 85.0%

Zn(HCO2CH2CH2CH2O)4C6H3C6H3C20H9N4(C6H2CH3(O(CH2)6C3H3N2)2) (425603-90-3) + 2-[2-(2-methoxyethoxy)ethoxy]ethylamine (74654-07-2,80506-64-5,869718-87-6) → (SP-4-2)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3,5-bis[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]](2-)-N(21),N(22),N(23),N(24))zinc(II) (253604-44-3)

Guidance literature:

With Et₃N; HATU; In N,N-dimethyl-formamide; Zn-complex was dissolved in DMF, ligand was added, cooled to 0°C,HATU and Et3N were added, stirred at 0°C for 2 h, stirred for 1 d at room temp. under N2 in the dark; solvent was distilled off under vac. at 40°C, residue was taken up in CH2Cl2/MeOH, purified by FC on SiO2 with CH2Cl2/MeOH, concd. in vacuo, dried under vac. overnight, GPC;

DOI:10.1002/1522-2675(200202)85:2<571::AID-HLCA571>3.0.CO;2-Y

upstream raw materials:

(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-(3,5-bis[[6-(1H-imidazole-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

Downstream raw materials:

(SP-4-2)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3,5-bis[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾)zinc(II)

Refernces