5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II)

Base Information

• Chemical Name: 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II)
• CAS No.: 1447738-10-4
• Molecular Formula: C₆₇H₄₀N₄Zn
• Molecular Weight: 966.471
• Mol file: 1447738-10-4.mol

Synonyms:5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II)

Chemical Property of 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II)

There total 2 articles about 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C67H42N4 + zinc(II) acetate dihydrate (5970-45-6) → 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II) (1447738-10-4)

Guidance literature:

In methanol; dichloromethane; at 20 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.jphotochem.2014.04.024

Reference yield: 97.0%

C67H42N4 + zinc(II) acetate dihydrate (5970-45-6) → 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II) (1447738-10-4)

Guidance literature:

In methanol; dichloromethane; Inert atmosphere;

DOI:10.1016/j.tet.2013.06.019

Reference yield: 25.0%

triphenyl-arsane (603-32-7) + 5,10,15-tris(9H-fluoren-2-yl)-20-(ethynylphenyl)porphyrinato zinc(II) (1447738-10-4) + C65H41IN4 → C132H80N8Zn + C73H44N4Zn (1447738-12-6) + C77H51AsN4

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triethylamine; tris-(o-tolyl)phosphine; In toluene; at 35 ℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere;

DOI:10.1016/j.tet.2013.06.019

upstream raw materials:

zinc(II) acetate dihydrate

Downstream raw materials:

C₇₃H₄₄N₄Zn